Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)

In the title compound, (C(5)H(7)N(2))(2)[Ni(H(2)O)(6)](SO(4))(2), the Ni(II) cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octa­hedral coordination environment. The [Ni(H(2)O)(6)](2+) ions are connected through an extensive network of O—H⋯O h...

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Detalles Bibliográficos
Autores principales: Sahbani, Thameur, Smirani Sta, Wajda, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914041/
https://www.ncbi.nlm.nih.gov/pubmed/24526957
http://dx.doi.org/10.1107/S1600536813032558
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author Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
author_facet Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
author_sort Sahbani, Thameur
collection PubMed
description In the title compound, (C(5)H(7)N(2))(2)[Ni(H(2)O)(6)](SO(4))(2), the Ni(II) cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octa­hedral coordination environment. The [Ni(H(2)O)(6)](2+) ions are connected through an extensive network of O—H⋯O hydrogen bonds to sulfate anions, leading to the formation of layers parallel to (001). The 4-amino­pyridinium cations are located between these layers and are connected to the anionic framework by N—H⋯O hydrogen bonds. Weak π–π inter­actions between the pyridine rings, with a centroid–centroid distance of 3.754 (9) Å, provide additional stability to the crystal packing.
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spelling pubmed-39140412014-02-13 Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate) Sahbani, Thameur Smirani Sta, Wajda Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(7)N(2))(2)[Ni(H(2)O)(6)](SO(4))(2), the Ni(II) cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octa­hedral coordination environment. The [Ni(H(2)O)(6)](2+) ions are connected through an extensive network of O—H⋯O hydrogen bonds to sulfate anions, leading to the formation of layers parallel to (001). The 4-amino­pyridinium cations are located between these layers and are connected to the anionic framework by N—H⋯O hydrogen bonds. Weak π–π inter­actions between the pyridine rings, with a centroid–centroid distance of 3.754 (9) Å, provide additional stability to the crystal packing. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914041/ /pubmed/24526957 http://dx.doi.org/10.1107/S1600536813032558 Text en © Sahbani et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sahbani, Thameur
Smirani Sta, Wajda
Rzaigui, Mohamed
Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title_full Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title_fullStr Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title_full_unstemmed Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title_short Bis(4-amino­pyridinium) hexa­aqua­nickel(II) bis­(sulfate)
title_sort bis(4-amino­pyridinium) hexa­aqua­nickel(ii) bis­(sulfate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914041/
https://www.ncbi.nlm.nih.gov/pubmed/24526957
http://dx.doi.org/10.1107/S1600536813032558
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AT smiranistawajda bis4aminopyridiniumhexaaquanickeliibissulfate
AT rzaiguimohamed bis4aminopyridiniumhexaaquanickeliibissulfate

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