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(1,4,7,10,13,16-Hexaoxacyclooctadecane-κ(6) O)bis(tetrahydrofuran-κO)potassium bis[(1,2,3,4-η)-anthracene]cobalt(−I) tetrahydrofuran monosolvate
The asymmetric unit of the title compound, [K(C(12)H(24)O(6))(C(4)H(8)O)(2)][Co(C(14)H(10))(2)]·C(4)H(8)O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetrahydrofuran solvent molecule. The potassium cation is situated at the centre of an 18-crown-6...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914043/ https://www.ncbi.nlm.nih.gov/pubmed/24526959 http://dx.doi.org/10.1107/S1600536813032510 |
Sumario: | The asymmetric unit of the title compound, [K(C(12)H(24)O(6))(C(4)H(8)O)(2)][Co(C(14)H(10))(2)]·C(4)H(8)O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetrahydrofuran solvent molecule. The potassium cation is situated at the centre of an 18-crown-6 molecule and between two tetrahydrofuran molecules, the latter coordinating above and below the mean plane formed by the O atoms of the crown ether molecule. The Co atom is coordinated by eight C atoms of two anthracene molecules in an η(4) manner. The third free tetrahydrofuran molecule shows orientational disorder on two partially occupied positions [occupancy ratio 0.561 (8):0.439 (8)]. |
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