(1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate

The asymmetric unit of the title compound, [K(C(12)H(24)O(6))(C(4)H(8)O)(2)][Co(C(14)H(10))(2)]·C(4)H(8)O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetra­hydro­furan solvent mol­ecule. The potassium cation is situated at the centre of an 18-crown-6...

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Detalles Bibliográficos
Autores principales: He, Haiyan, Klein, Wilhelm, Fässler, Thomas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914043/
https://www.ncbi.nlm.nih.gov/pubmed/24526959
http://dx.doi.org/10.1107/S1600536813032510
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author He, Haiyan
Klein, Wilhelm
Fässler, Thomas F.
author_facet He, Haiyan
Klein, Wilhelm
Fässler, Thomas F.
author_sort He, Haiyan
collection PubMed
description The asymmetric unit of the title compound, [K(C(12)H(24)O(6))(C(4)H(8)O)(2)][Co(C(14)H(10))(2)]·C(4)H(8)O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetra­hydro­furan solvent mol­ecule. The potassium cation is situated at the centre of an 18-crown-6 mol­ecule and between two tetra­hydro­furan mol­ecules, the latter coordin­ating above and below the mean plane formed by the O atoms of the crown ether mol­ecule. The Co atom is coordinated by eight C atoms of two anthracene mol­ecules in an η(4) manner. The third free tetra­hydro­furan mol­ecule shows orientational disorder on two partially occupied positions [occupancy ratio 0.561 (8):0.439 (8)].
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spelling pubmed-39140432014-02-13 (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate He, Haiyan Klein, Wilhelm Fässler, Thomas F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [K(C(12)H(24)O(6))(C(4)H(8)O)(2)][Co(C(14)H(10))(2)]·C(4)H(8)O, consists of one cationic potassium complex, one anionic cobalt dianthracene complex and one tetra­hydro­furan solvent mol­ecule. The potassium cation is situated at the centre of an 18-crown-6 mol­ecule and between two tetra­hydro­furan mol­ecules, the latter coordin­ating above and below the mean plane formed by the O atoms of the crown ether mol­ecule. The Co atom is coordinated by eight C atoms of two anthracene mol­ecules in an η(4) manner. The third free tetra­hydro­furan mol­ecule shows orientational disorder on two partially occupied positions [occupancy ratio 0.561 (8):0.439 (8)]. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914043/ /pubmed/24526959 http://dx.doi.org/10.1107/S1600536813032510 Text en © He et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
He, Haiyan
Klein, Wilhelm
Fässler, Thomas F.
(1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title_full (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title_fullStr (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title_full_unstemmed (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title_short (1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane-κ(6) O)bis­(tetra­hydro­furan-κO)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−I) tetra­hydro­furan monosolvate
title_sort (1,4,7,10,13,16-hexaoxa­cyclo­octa­decane-κ(6) o)bis­(tetra­hydro­furan-κo)potassium bis­[(1,2,3,4-η)-anthracene]cobalt(−i) tetra­hydro­furan monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914043/
https://www.ncbi.nlm.nih.gov/pubmed/24526959
http://dx.doi.org/10.1107/S1600536813032510
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AT fasslerthomasf 147101316hexaoxacyclooctadecanek6obistetrahydrofurankopotassiumbis1234ēanthracenecobaltitetrahydrofuranmonosolvate

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