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2,6-Bis(bromomethyl)pyridine
In the title molecule, C(7)H(7)Br(2)N, the C—Br vectors of the bromomethyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the molecules related by a c-glide-plane operation are arranged into stacks along the c axis, with ce...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914046/ https://www.ncbi.nlm.nih.gov/pubmed/24526985 http://dx.doi.org/10.1107/S1600536813032364 |
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author | Cuzan, Olesea Straistari, Tatiana Turta, Constantin Réglier, Marius |
author_facet | Cuzan, Olesea Straistari, Tatiana Turta, Constantin Réglier, Marius |
author_sort | Cuzan, Olesea |
collection | PubMed |
description | In the title molecule, C(7)H(7)Br(2)N, the C—Br vectors of the bromomethyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the molecules related by a c-glide-plane operation are arranged into stacks along the c axis, with centroid–centroid distances between neighboring aromatic rings of 3.778 (2) Å. A short Br⋯Br contact of 3.6025 (11) Å is observed within a pair of inversion-related molecules. |
format | Online Article Text |
id | pubmed-3914046 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140462014-02-13 2,6-Bis(bromomethyl)pyridine Cuzan, Olesea Straistari, Tatiana Turta, Constantin Réglier, Marius Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(7)H(7)Br(2)N, the C—Br vectors of the bromomethyl groups extend to opposite sides of the pyridine ring and are oriented nearly perpendicular to its plane. In the crystal, the molecules related by a c-glide-plane operation are arranged into stacks along the c axis, with centroid–centroid distances between neighboring aromatic rings of 3.778 (2) Å. A short Br⋯Br contact of 3.6025 (11) Å is observed within a pair of inversion-related molecules. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914046/ /pubmed/24526985 http://dx.doi.org/10.1107/S1600536813032364 Text en © Cuzan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Cuzan, Olesea Straistari, Tatiana Turta, Constantin Réglier, Marius 2,6-Bis(bromomethyl)pyridine |
title | 2,6-Bis(bromomethyl)pyridine |
title_full | 2,6-Bis(bromomethyl)pyridine |
title_fullStr | 2,6-Bis(bromomethyl)pyridine |
title_full_unstemmed | 2,6-Bis(bromomethyl)pyridine |
title_short | 2,6-Bis(bromomethyl)pyridine |
title_sort | 2,6-bis(bromomethyl)pyridine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914046/ https://www.ncbi.nlm.nih.gov/pubmed/24526985 http://dx.doi.org/10.1107/S1600536813032364 |
work_keys_str_mv | AT cuzanolesea 26bisbromomethylpyridine AT straistaritatiana 26bisbromomethylpyridine AT turtaconstantin 26bisbromomethylpyridine AT regliermarius 26bisbromomethylpyridine |