Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide

In the title quaternary ammonium salt, C(55)H(61)N(4) (+)·I(−), all three N,N-di­benzyl­ethanamine, –(CH(2))(2)N(CH(2)C(6)H(5))(2), groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between t...

Descripción completa

Detalles Bibliográficos
Autores principales: Bello, Mollie J., Brady, Sarah E., Zakharov, Lev N., Tyler, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914047/
https://www.ncbi.nlm.nih.gov/pubmed/24526992
http://dx.doi.org/10.1107/S1600536813031607
Descripción
Sumario:In the title quaternary ammonium salt, C(55)H(61)N(4) (+)·I(−), all three N,N-di­benzyl­ethanamine, –(CH(2))(2)N(CH(2)C(6)H(5))(2), groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between the phenyl rings in these groups are different as well [58.21 (4), 43.73 (4) and 76.72 (5)°]. In the crystal, the I(−) anions fill empty spaces between the bulky cations. The cations and anions are linked by weak C—H⋯I inter­actions, forming a chain along [110].

Ejemplares similares