Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide

In the title quaternary ammonium salt, C(55)H(61)N(4) (+)·I(−), all three N,N-di­benzyl­ethanamine, –(CH(2))(2)N(CH(2)C(6)H(5))(2), groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between t...

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Detalles Bibliográficos
Autores principales: Bello, Mollie J., Brady, Sarah E., Zakharov, Lev N., Tyler, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914047/
https://www.ncbi.nlm.nih.gov/pubmed/24526992
http://dx.doi.org/10.1107/S1600536813031607
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author Bello, Mollie J.
Brady, Sarah E.
Zakharov, Lev N.
Tyler, David R.
author_facet Bello, Mollie J.
Brady, Sarah E.
Zakharov, Lev N.
Tyler, David R.
author_sort Bello, Mollie J.
collection PubMed
description In the title quaternary ammonium salt, C(55)H(61)N(4) (+)·I(−), all three N,N-di­benzyl­ethanamine, –(CH(2))(2)N(CH(2)C(6)H(5))(2), groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between the phenyl rings in these groups are different as well [58.21 (4), 43.73 (4) and 76.72 (5)°]. In the crystal, the I(−) anions fill empty spaces between the bulky cations. The cations and anions are linked by weak C—H⋯I inter­actions, forming a chain along [110].
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spelling pubmed-39140472014-02-13 Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide Bello, Mollie J. Brady, Sarah E. Zakharov, Lev N. Tyler, David R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title quaternary ammonium salt, C(55)H(61)N(4) (+)·I(−), all three N,N-di­benzyl­ethanamine, –(CH(2))(2)N(CH(2)C(6)H(5))(2), groups have different conformations. The N—C—C—N torsion angles are significantly different [89.86 (13), 162.61 (10) and 175.70 (10)°] and the dihedral angles between the phenyl rings in these groups are different as well [58.21 (4), 43.73 (4) and 76.72 (5)°]. In the crystal, the I(−) anions fill empty spaces between the bulky cations. The cations and anions are linked by weak C—H⋯I inter­actions, forming a chain along [110]. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914047/ /pubmed/24526992 http://dx.doi.org/10.1107/S1600536813031607 Text en © Bello et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bello, Mollie J.
Brady, Sarah E.
Zakharov, Lev N.
Tyler, David R.
Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title_full Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title_fullStr Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title_full_unstemmed Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title_short Benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
title_sort benzyl­tris­[2-(di­benzyl­amino)­eth­yl]ammonium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914047/
https://www.ncbi.nlm.nih.gov/pubmed/24526992
http://dx.doi.org/10.1107/S1600536813031607
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