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4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide

There are two independent mol­ecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia­zole ring; the angles around the N atoms are between 11...

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Autores principales: Carballo, Rubén M., Hernández-Ortega, Simón, Padilla-Montaño, Nayely, Reyes-Martínez, Reyna, Mirón-López, Gumersindo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914048/
https://www.ncbi.nlm.nih.gov/pubmed/24526999
http://dx.doi.org/10.1107/S1600536813032145
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author Carballo, Rubén M.
Hernández-Ortega, Simón
Padilla-Montaño, Nayely
Reyes-Martínez, Reyna
Mirón-López, Gumersindo
author_facet Carballo, Rubén M.
Hernández-Ortega, Simón
Padilla-Montaño, Nayely
Reyes-Martínez, Reyna
Mirón-López, Gumersindo
author_sort Carballo, Rubén M.
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia­zole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methyl­phenyl­sulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two mol­ecules. The thia­zole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H⋯O inter­actions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent mol­ecules into inversion dimers.
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spelling pubmed-39140482014-02-13 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide Carballo, Rubén M. Hernández-Ortega, Simón Padilla-Montaño, Nayely Reyes-Martínez, Reyna Mirón-López, Gumersindo Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thia­zole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methyl­phenyl­sulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two mol­ecules. The thia­zole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H⋯O inter­actions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent mol­ecules into inversion dimers. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914048/ /pubmed/24526999 http://dx.doi.org/10.1107/S1600536813032145 Text en © Carballo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Carballo, Rubén M.
Hernández-Ortega, Simón
Padilla-Montaño, Nayely
Reyes-Martínez, Reyna
Mirón-López, Gumersindo
4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title_full 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title_fullStr 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title_full_unstemmed 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title_short 4-Methyl-N-(4-methyl­phenyl­sulfon­yl)-N-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
title_sort 4-methyl-n-(4-methyl­phenyl­sulfon­yl)-n-[4-(4-methyl­phen­yl)-1,3-thia­zol-2-yl]benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914048/
https://www.ncbi.nlm.nih.gov/pubmed/24526999
http://dx.doi.org/10.1107/S1600536813032145
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