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4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide
There are two independent molecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 11...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914048/ https://www.ncbi.nlm.nih.gov/pubmed/24526999 http://dx.doi.org/10.1107/S1600536813032145 |
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author | Carballo, Rubén M. Hernández-Ortega, Simón Padilla-Montaño, Nayely Reyes-Martínez, Reyna Mirón-López, Gumersindo |
author_facet | Carballo, Rubén M. Hernández-Ortega, Simón Padilla-Montaño, Nayely Reyes-Martínez, Reyna Mirón-López, Gumersindo |
author_sort | Carballo, Rubén M. |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methylphenylsulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two molecules. The thiazole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H⋯O interactions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent molecules into inversion dimers. |
format | Online Article Text |
id | pubmed-3914048 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140482014-02-13 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide Carballo, Rubén M. Hernández-Ortega, Simón Padilla-Montaño, Nayely Reyes-Martínez, Reyna Mirón-López, Gumersindo Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(24)H(22)N(2)O(4)S(3). In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methylphenylsulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two molecules. The thiazole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H⋯O interactions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent molecules into inversion dimers. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914048/ /pubmed/24526999 http://dx.doi.org/10.1107/S1600536813032145 Text en © Carballo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Carballo, Rubén M. Hernández-Ortega, Simón Padilla-Montaño, Nayely Reyes-Martínez, Reyna Mirón-López, Gumersindo 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title | 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title_full | 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title_fullStr | 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title_full_unstemmed | 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title_short | 4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
title_sort | 4-methyl-n-(4-methylphenylsulfonyl)-n-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914048/ https://www.ncbi.nlm.nih.gov/pubmed/24526999 http://dx.doi.org/10.1107/S1600536813032145 |
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