(E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol

In the title compound, C(21)H(26)O(2)SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra­molecular C—H⋯O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O—H...

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Autores principales: Wu, Jinglan, Chen, Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914049/
https://www.ncbi.nlm.nih.gov/pubmed/24527011
http://dx.doi.org/10.1107/S1600536813032182
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author Wu, Jinglan
Chen, Chen
author_facet Wu, Jinglan
Chen, Chen
author_sort Wu, Jinglan
collection PubMed
description In the title compound, C(21)H(26)O(2)SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra­molecular C—H⋯O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O—H⋯O=S hydrogen bonds, generating R (2) (2)(14) loops. Weak C—H⋯O inter­actions also occur.
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spelling pubmed-39140492014-02-13 (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol Wu, Jinglan Chen, Chen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(26)O(2)SSe, the S atom adopts a pyramidal geometry (bond-angle sum = 304°) and the n-butyl chain shows an extended conformation. An intra­molecular C—H⋯O hydrogen bond closes an S(8) ring. In the crystal, inversion dimers are formed with molecules linked by pairs of O—H⋯O=S hydrogen bonds, generating R (2) (2)(14) loops. Weak C—H⋯O inter­actions also occur. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914049/ /pubmed/24527011 http://dx.doi.org/10.1107/S1600536813032182 Text en © Wu and Chen 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, Jinglan
Chen, Chen
(E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title_full (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title_fullStr (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title_full_unstemmed (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title_short (E)-2-Methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
title_sort (e)-2-methyl-3-phenyl­selanyl-4-(phenyl­sulfin­yl)oct-3-en-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914049/
https://www.ncbi.nlm.nih.gov/pubmed/24527011
http://dx.doi.org/10.1107/S1600536813032182
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