1-(Bromo­mercurio)ferrocene

The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(5)H(4)BrHg)], contains two independent mol­ecules, A and B, in which the Hg—C bond lengths are 2.045 (6) and 2.046 (6) Å, the Hg—Br bond lengths are 2.4511 (9) and 2.4562 (7) Å, and the C—Hg—Br angles are 176.42 (17) and 177.32 (17)°. The tw...

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Detalles Bibliográficos
Autores principales: Breunig, Jens M., Lerner, Hans-Wolfram, Bats, Jan W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914051/
https://www.ncbi.nlm.nih.gov/pubmed/24526943
http://dx.doi.org/10.1107/S1600536813032923
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author Breunig, Jens M.
Lerner, Hans-Wolfram
Bats, Jan W.
author_facet Breunig, Jens M.
Lerner, Hans-Wolfram
Bats, Jan W.
author_sort Breunig, Jens M.
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(5)H(4)BrHg)], contains two independent mol­ecules, A and B, in which the Hg—C bond lengths are 2.045 (6) and 2.046 (6) Å, the Hg—Br bond lengths are 2.4511 (9) and 2.4562 (7) Å, and the C—Hg—Br angles are 176.42 (17) and 177.32 (17)°. The two cyclo­penta­dienyl rings of mol­ecule A are eclipsed, while those of mol­ecule B are almost staggered. The HgBr groups are connected by inter­molecular Hg⋯Br contacts of 3.3142 (9)–3.4895 (11) Å, forming layers parallel to (001). These layers contain both four-membered (HgBr)(2) and eight-membered (HgBr)(4) rings. Ferrocene–ferrocene C—H⋯π contacts connect the mol­ecular layers along the c-axis direction.
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spelling pubmed-39140512014-02-13 1-(Bromo­mercurio)ferrocene Breunig, Jens M. Lerner, Hans-Wolfram Bats, Jan W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(5)H(4)BrHg)], contains two independent mol­ecules, A and B, in which the Hg—C bond lengths are 2.045 (6) and 2.046 (6) Å, the Hg—Br bond lengths are 2.4511 (9) and 2.4562 (7) Å, and the C—Hg—Br angles are 176.42 (17) and 177.32 (17)°. The two cyclo­penta­dienyl rings of mol­ecule A are eclipsed, while those of mol­ecule B are almost staggered. The HgBr groups are connected by inter­molecular Hg⋯Br contacts of 3.3142 (9)–3.4895 (11) Å, forming layers parallel to (001). These layers contain both four-membered (HgBr)(2) and eight-membered (HgBr)(4) rings. Ferrocene–ferrocene C—H⋯π contacts connect the mol­ecular layers along the c-axis direction. International Union of Crystallography 2013-12-11 /pmc/articles/PMC3914051/ /pubmed/24526943 http://dx.doi.org/10.1107/S1600536813032923 Text en © Breunig et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Breunig, Jens M.
Lerner, Hans-Wolfram
Bats, Jan W.
1-(Bromo­mercurio)ferrocene
title 1-(Bromo­mercurio)ferrocene
title_full 1-(Bromo­mercurio)ferrocene
title_fullStr 1-(Bromo­mercurio)ferrocene
title_full_unstemmed 1-(Bromo­mercurio)ferrocene
title_short 1-(Bromo­mercurio)ferrocene
title_sort 1-(bromo­mercurio)ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914051/
https://www.ncbi.nlm.nih.gov/pubmed/24526943
http://dx.doi.org/10.1107/S1600536813032923
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