Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]

The title dinuclear half-sandwich complex, [CpTi(OCH=CH(2))(μ(2)-N-iPr)](2) (Cp = cyclo­penta­dien­yl; iPr = isopropyl), was ob­tained from the reaction of Cp(2)TiCl(2), n-butyl­lithium and iso­propyl­amine in tetra­hydro­furan. Each Ti(IV) atom is coordinated by one Cp ligand, one vin­yloxy unit an...

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Detalles Bibliográficos
Autores principales: Haehnel, Martin, Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914052/
https://www.ncbi.nlm.nih.gov/pubmed/24526944
http://dx.doi.org/10.1107/S1600536813033072
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author Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
author_facet Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
author_sort Haehnel, Martin
collection PubMed
description The title dinuclear half-sandwich complex, [CpTi(OCH=CH(2))(μ(2)-N-iPr)](2) (Cp = cyclo­penta­dien­yl; iPr = isopropyl), was ob­tained from the reaction of Cp(2)TiCl(2), n-butyl­lithium and iso­propyl­amine in tetra­hydro­furan. Each Ti(IV) atom is coordinated by one Cp ligand, one vin­yloxy unit and two bridging imido groups in a strongly distorted tetra­hedral geometry. There are two half mol­ecules in the asymmetric unit, such that whole mol­ecules being generated by inversion symmetry.
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spelling pubmed-39140522014-02-13 Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)] Haehnel, Martin Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title dinuclear half-sandwich complex, [CpTi(OCH=CH(2))(μ(2)-N-iPr)](2) (Cp = cyclo­penta­dien­yl; iPr = isopropyl), was ob­tained from the reaction of Cp(2)TiCl(2), n-butyl­lithium and iso­propyl­amine in tetra­hydro­furan. Each Ti(IV) atom is coordinated by one Cp ligand, one vin­yloxy unit and two bridging imido groups in a strongly distorted tetra­hedral geometry. There are two half mol­ecules in the asymmetric unit, such that whole mol­ecules being generated by inversion symmetry. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914052/ /pubmed/24526944 http://dx.doi.org/10.1107/S1600536813033072 Text en © Haehnel et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Haehnel, Martin
Spannenberg, Anke
Rosenthal, Uwe
Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title_full Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title_fullStr Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title_full_unstemmed Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title_short Bis(μ(2)-iso­propyl­imido-κ(2) N:N)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]
title_sort bis(μ(2)-iso­propyl­imido-κ(2) n:n)bis­[(η(5)-cyclo­penta­dien­yl)(ethenolato-κo)titanium(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914052/
https://www.ncbi.nlm.nih.gov/pubmed/24526944
http://dx.doi.org/10.1107/S1600536813033072
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AT rosenthaluwe bism2isopropylimidok2nnbisē5cyclopentadienylethenolatokotitaniumiv

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