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trans-Dichloridobis(pyridazine-κN)palladium(II)
The title compound, [PdCl(2)(C(4)H(4)N(2))(2)], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one compl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914053/ https://www.ncbi.nlm.nih.gov/pubmed/24526945 http://dx.doi.org/10.1107/S1600536813032716 |
| Sumario: | The title compound, [PdCl(2)(C(4)H(4)N(2))(2)], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd—Cl bond is almost perpendicular [89.4 (1)°], while the other is tilted with an angle of 60.0 (1)°. In the crystal, weak C⋯H—N hydrogen bonds and C⋯H—Cl interactions connect the two independent complex molecules. |
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