trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)

The title compound, [PdCl(2)(C(4)H(4)N(2))(2)], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one compl...

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Detalles Bibliográficos
Autores principales: Laramée, Baptiste, Hanan, Garry S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914053/
https://www.ncbi.nlm.nih.gov/pubmed/24526945
http://dx.doi.org/10.1107/S1600536813032716
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author Laramée, Baptiste
Hanan, Garry S.
author_facet Laramée, Baptiste
Hanan, Garry S.
author_sort Laramée, Baptiste
collection PubMed
description The title compound, [PdCl(2)(C(4)H(4)N(2))(2)], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd—Cl bond is almost perpendicular [89.4 (1)°], while the other is tilted with an angle of 60.0 (1)°. In the crystal, weak C⋯H—N hydrogen bonds and C⋯H—Cl inter­actions connect the two independent complex mol­ecules.
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spelling pubmed-39140532014-02-13 trans-Di­chlorido­bis­(pyridazine-κN)palladium(II) Laramée, Baptiste Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(4)H(4)N(2))(2)], contains two crystallographically unique complexes; the Pd(II) atom lies on an inversion center in both cases. The two pyridazine units bonded to the Pd(II) atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd—Cl bond is almost perpendicular [89.4 (1)°], while the other is tilted with an angle of 60.0 (1)°. In the crystal, weak C⋯H—N hydrogen bonds and C⋯H—Cl inter­actions connect the two independent complex mol­ecules. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914053/ /pubmed/24526945 http://dx.doi.org/10.1107/S1600536813032716 Text en © Laramée and Hanan 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Laramée, Baptiste
Hanan, Garry S.
trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title_full trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title_fullStr trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title_full_unstemmed trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title_short trans-Di­chlorido­bis­(pyridazine-κN)palladium(II)
title_sort trans-di­chlorido­bis­(pyridazine-κn)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914053/
https://www.ncbi.nlm.nih.gov/pubmed/24526945
http://dx.doi.org/10.1107/S1600536813032716
work_keys_str_mv AT larameebaptiste transdichloridobispyridazineknpalladiumii
AT hanangarrys transdichloridobispyridazineknpalladiumii

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