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Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2) N (3),O)nickel(II) dihydrate
In the title complex, [Ni(C(6)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazolesulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octahedral configuration....
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914054/ https://www.ncbi.nlm.nih.gov/pubmed/24526946 http://dx.doi.org/10.1107/S1600536813032169 |
| _version_ | 1782302334046437376 |
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| author | Purdy, Andrew P. Butcher, Ray J. |
| author_facet | Purdy, Andrew P. Butcher, Ray J. |
| author_sort | Purdy, Andrew P. |
| collection | PubMed |
| description | In the title complex, [Ni(C(6)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazolesulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octahedral configuration. The crystal structure displays O—H⋯O and N—H⋯O hydrogen bonds, which connect the components into an extended three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3914054 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39140542014-02-13 Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2) N (3),O)nickel(II) dihydrate Purdy, Andrew P. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(6)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazolesulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octahedral configuration. The crystal structure displays O—H⋯O and N—H⋯O hydrogen bonds, which connect the components into an extended three-dimensional network. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914054/ /pubmed/24526946 http://dx.doi.org/10.1107/S1600536813032169 Text en © Purdy and Butcher 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Purdy, Andrew P. Butcher, Ray J. Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2) N (3),O)nickel(II) dihydrate |
| title | Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
N
(3),O)nickel(II) dihydrate |
| title_full | Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
N
(3),O)nickel(II) dihydrate |
| title_fullStr | Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
N
(3),O)nickel(II) dihydrate |
| title_full_unstemmed | Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
N
(3),O)nickel(II) dihydrate |
| title_short | Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
N
(3),O)nickel(II) dihydrate |
| title_sort | diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ(2)
n
(3),o)nickel(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914054/ https://www.ncbi.nlm.nih.gov/pubmed/24526946 http://dx.doi.org/10.1107/S1600536813032169 |
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