Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)

The title compound, [Bi(C(4)H(8)NOS(2))(2)I(C(12)H(8)N(2))], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate...

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Detalles Bibliográficos
Autores principales: Li, Feng, Yin, Handong, Wu, Guoxing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914055/
https://www.ncbi.nlm.nih.gov/pubmed/24526948
http://dx.doi.org/10.1107/S1600536813033515
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author Li, Feng
Yin, Handong
Wu, Guoxing
author_facet Li, Feng
Yin, Handong
Wu, Guoxing
author_sort Li, Feng
collection PubMed
description The title compound, [Bi(C(4)H(8)NOS(2))(2)I(C(12)H(8)N(2))], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa­hedral geometry.
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spelling pubmed-39140552014-02-13 Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III) Li, Feng Yin, Handong Wu, Guoxing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Bi(C(4)H(8)NOS(2))(2)I(C(12)H(8)N(2))], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi­thio­ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa­hedral geometry. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914055/ /pubmed/24526948 http://dx.doi.org/10.1107/S1600536813033515 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Feng
Yin, Handong
Wu, Guoxing
Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title_full Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title_fullStr Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title_full_unstemmed Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title_short Iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)bis­muth(III)
title_sort iodido­bis­(morpholine-4-carbodi­thio­ato-κ(2) s,s′)(1,10-phenanthroline-κ(2) n,n′)bis­muth(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914055/
https://www.ncbi.nlm.nih.gov/pubmed/24526948
http://dx.doi.org/10.1107/S1600536813033515
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AT wuguoxing iodidobismorpholine4carbodithioatok2ss110phenanthrolinek2nnbismuthiii

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