Bis(μ(2)-benzoato-κ(2) O:O′)bis­[(benzoato-κ(2) O,O′)bis(4,4′-bi­pyridine-κN)cobalt(II)]–benzoic acid (1/6)

In the title compound, [Co(2)(C(7)H(5)O(2))(4)(C(10)H(8)N(2))(4)]·6C(6)H(5)COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol­ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical posi...

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Detalles Bibliográficos
Autores principales: Peña-Rodríguez, Rodolfo, Rivera, José María, Colorado-Peralta, Raúl, Duarte-Hernández, Angélica María, Flores-Parra, Angelina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914056/
https://www.ncbi.nlm.nih.gov/pubmed/24526949
http://dx.doi.org/10.1107/S1600536813033357
Descripción
Sumario:In the title compound, [Co(2)(C(7)H(5)O(2))(4)(C(10)H(8)N(2))(4)]·6C(6)H(5)COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol­ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4′-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. In the crystal, the three-dimensional network is assembled by O—H⋯O and C—H⋯O hydrogen bonds.

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