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Bis(μ(2)-benzoato-κ(2) O:O′)bis[(benzoato-κ(2) O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6)
In the title compound, [Co(2)(C(7)H(5)O(2))(4)(C(10)H(8)N(2))(4)]·6C(6)H(5)COOH, the centrosymmetric cobalt dimer co-crystallizes with six molecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical posi...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914056/ https://www.ncbi.nlm.nih.gov/pubmed/24526949 http://dx.doi.org/10.1107/S1600536813033357 |
| _version_ | 1782302334522490880 |
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| author | Peña-Rodríguez, Rodolfo Rivera, José María Colorado-Peralta, Raúl Duarte-Hernández, Angélica María Flores-Parra, Angelina |
| author_facet | Peña-Rodríguez, Rodolfo Rivera, José María Colorado-Peralta, Raúl Duarte-Hernández, Angélica María Flores-Parra, Angelina |
| author_sort | Peña-Rodríguez, Rodolfo |
| collection | PubMed |
| description | In the title compound, [Co(2)(C(7)H(5)O(2))(4)(C(10)H(8)N(2))(4)]·6C(6)H(5)COOH, the centrosymmetric cobalt dimer co-crystallizes with six molecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4′-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. In the crystal, the three-dimensional network is assembled by O—H⋯O and C—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3914056 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39140562014-02-13 Bis(μ(2)-benzoato-κ(2) O:O′)bis[(benzoato-κ(2) O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) Peña-Rodríguez, Rodolfo Rivera, José María Colorado-Peralta, Raúl Duarte-Hernández, Angélica María Flores-Parra, Angelina Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(7)H(5)O(2))(4)(C(10)H(8)N(2))(4)]·6C(6)H(5)COOH, the centrosymmetric cobalt dimer co-crystallizes with six molecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4′-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. In the crystal, the three-dimensional network is assembled by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2013-12-18 /pmc/articles/PMC3914056/ /pubmed/24526949 http://dx.doi.org/10.1107/S1600536813033357 Text en © Peña-Rodríguez et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Peña-Rodríguez, Rodolfo Rivera, José María Colorado-Peralta, Raúl Duarte-Hernández, Angélica María Flores-Parra, Angelina Bis(μ(2)-benzoato-κ(2) O:O′)bis[(benzoato-κ(2) O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title | Bis(μ(2)-benzoato-κ(2)
O:O′)bis[(benzoato-κ(2)
O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title_full | Bis(μ(2)-benzoato-κ(2)
O:O′)bis[(benzoato-κ(2)
O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title_fullStr | Bis(μ(2)-benzoato-κ(2)
O:O′)bis[(benzoato-κ(2)
O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title_full_unstemmed | Bis(μ(2)-benzoato-κ(2)
O:O′)bis[(benzoato-κ(2)
O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title_short | Bis(μ(2)-benzoato-κ(2)
O:O′)bis[(benzoato-κ(2)
O,O′)bis(4,4′-bipyridine-κN)cobalt(II)]–benzoic acid (1/6) |
| title_sort | bis(μ(2)-benzoato-κ(2)
o:o′)bis[(benzoato-κ(2)
o,o′)bis(4,4′-bipyridine-κn)cobalt(ii)]–benzoic acid (1/6) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914056/ https://www.ncbi.nlm.nih.gov/pubmed/24526949 http://dx.doi.org/10.1107/S1600536813033357 |
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