catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]

The title compound, [Co(C(24)H(28)N(2)O(6))](n), crystallizes as infinite chains related to one another by inversion centers, giving a centrosymmetric coordination polymer. The Co(II) ion, situated on a twofold rotation axis, forms a complex with the crown-4 moiety of the 3,3′-[(1,7-dioxa-4,10-di­az...

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Detalles Bibliográficos
Autores principales: Liao, Liang, Ingram, Conrad W., Bacsa, John, Parker, Cass
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914058/
https://www.ncbi.nlm.nih.gov/pubmed/24526951
http://dx.doi.org/10.1107/S1600536813032832
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author Liao, Liang
Ingram, Conrad W.
Bacsa, John
Parker, Cass
author_facet Liao, Liang
Ingram, Conrad W.
Bacsa, John
Parker, Cass
author_sort Liao, Liang
collection PubMed
description The title compound, [Co(C(24)H(28)N(2)O(6))](n), crystallizes as infinite chains related to one another by inversion centers, giving a centrosymmetric coordination polymer. The Co(II) ion, situated on a twofold rotation axis, forms a complex with the crown-4 moiety of the 3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­do­decane-4,10-di­yl)bis­(meth­ylene)]dibenzoate anion. The dis­torted octahedral coordination sphere of the Co(II) ion is completed by two carboxyl­ate O atoms from two bridging intra-chain ligands. Metallomacrocyclic rings of 16 atoms are present, with each ring containing two Co(II) ions and 14 atoms from the bridging ligands. These units repeat as infinite zigzag chains along [101].
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spelling pubmed-39140582014-02-13 catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)] Liao, Liang Ingram, Conrad W. Bacsa, John Parker, Cass Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(24)H(28)N(2)O(6))](n), crystallizes as infinite chains related to one another by inversion centers, giving a centrosymmetric coordination polymer. The Co(II) ion, situated on a twofold rotation axis, forms a complex with the crown-4 moiety of the 3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­do­decane-4,10-di­yl)bis­(meth­ylene)]dibenzoate anion. The dis­torted octahedral coordination sphere of the Co(II) ion is completed by two carboxyl­ate O atoms from two bridging intra-chain ligands. Metallomacrocyclic rings of 16 atoms are present, with each ring containing two Co(II) ions and 14 atoms from the bridging ligands. These units repeat as infinite zigzag chains along [101]. International Union of Crystallography 2013-12-18 /pmc/articles/PMC3914058/ /pubmed/24526951 http://dx.doi.org/10.1107/S1600536813032832 Text en © Liao et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liao, Liang
Ingram, Conrad W.
Bacsa, John
Parker, Cass
catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title_full catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title_fullStr catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title_full_unstemmed catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title_short catena-Poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(II)]
title_sort catena-poly[{μ(3)-3,3′-[(1,7-dioxa-4,10-di­aza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914058/
https://www.ncbi.nlm.nih.gov/pubmed/24526951
http://dx.doi.org/10.1107/S1600536813032832
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