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Tetra-μ-acetato-κ(8) O:O′-bis­[(pyridine-2-carbo­nitrile-κN (1))copper(II)]

The title binuclear compound, [Cu(2)(CH(3)COO)(4)(C(6)H(4)N(2))(2)], lies about an inversion center, with the Cu(II) cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu⋯Cu distance is 2.5997 (15) Å. In the crystal, mol­ecules ar...

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Detalles Bibliográficos
Autores principales: Luo, Mei, Wang, Lei, Zhang, Jing-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914060/
https://www.ncbi.nlm.nih.gov/pubmed/24526953
http://dx.doi.org/10.1107/S1600536813034120
Descripción
Sumario:The title binuclear compound, [Cu(2)(CH(3)COO)(4)(C(6)H(4)N(2))(2)], lies about an inversion center, with the Cu(II) cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu⋯Cu distance is 2.5997 (15) Å. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯N hydrogen bonds into a three-dimensional supra­molecular architecture. The crystal studied was a non-merohedral twin with a minor twin component of 4.1 (1)%.