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Tetra-μ-acetato-κ(8) O:O′-bis[(pyridine-2-carbonitrile-κN (1))copper(II)]
The title binuclear compound, [Cu(2)(CH(3)COO)(4)(C(6)H(4)N(2))(2)], lies about an inversion center, with the Cu(II) cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu⋯Cu distance is 2.5997 (15) Å. In the crystal, molecules ar...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914060/ https://www.ncbi.nlm.nih.gov/pubmed/24526953 http://dx.doi.org/10.1107/S1600536813034120 |
| _version_ | 1782302335467257856 |
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| author | Luo, Mei Wang, Lei Zhang, Jing-Cheng |
| author_facet | Luo, Mei Wang, Lei Zhang, Jing-Cheng |
| author_sort | Luo, Mei |
| collection | PubMed |
| description | The title binuclear compound, [Cu(2)(CH(3)COO)(4)(C(6)H(4)N(2))(2)], lies about an inversion center, with the Cu(II) cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu⋯Cu distance is 2.5997 (15) Å. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯N hydrogen bonds into a three-dimensional supramolecular architecture. The crystal studied was a non-merohedral twin with a minor twin component of 4.1 (1)%. |
| format | Online Article Text |
| id | pubmed-3914060 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39140602014-02-13 Tetra-μ-acetato-κ(8) O:O′-bis[(pyridine-2-carbonitrile-κN (1))copper(II)] Luo, Mei Wang, Lei Zhang, Jing-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title binuclear compound, [Cu(2)(CH(3)COO)(4)(C(6)H(4)N(2))(2)], lies about an inversion center, with the Cu(II) cation bridged by four acetate anions and coordinated by a pyridine N atom in a distorted square-pyramidal geometry. The Cu⋯Cu distance is 2.5997 (15) Å. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯N hydrogen bonds into a three-dimensional supramolecular architecture. The crystal studied was a non-merohedral twin with a minor twin component of 4.1 (1)%. International Union of Crystallography 2013-12-24 /pmc/articles/PMC3914060/ /pubmed/24526953 http://dx.doi.org/10.1107/S1600536813034120 Text en © Luo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Luo, Mei Wang, Lei Zhang, Jing-Cheng Tetra-μ-acetato-κ(8) O:O′-bis[(pyridine-2-carbonitrile-κN (1))copper(II)] |
| title | Tetra-μ-acetato-κ(8)
O:O′-bis[(pyridine-2-carbonitrile-κN
(1))copper(II)] |
| title_full | Tetra-μ-acetato-κ(8)
O:O′-bis[(pyridine-2-carbonitrile-κN
(1))copper(II)] |
| title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis[(pyridine-2-carbonitrile-κN
(1))copper(II)] |
| title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis[(pyridine-2-carbonitrile-κN
(1))copper(II)] |
| title_short | Tetra-μ-acetato-κ(8)
O:O′-bis[(pyridine-2-carbonitrile-κN
(1))copper(II)] |
| title_sort | tetra-μ-acetato-κ(8)
o:o′-bis[(pyridine-2-carbonitrile-κn
(1))copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914060/ https://www.ncbi.nlm.nih.gov/pubmed/24526953 http://dx.doi.org/10.1107/S1600536813034120 |
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