Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc

In the title compound, [ZnCl(2)(C(6)H(8)N(2)O(2)S)(2)], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra­hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn—Cl = 2.2288 (16) Å and Zn—N...

Descripción completa

Detalles Bibliográficos
Autores principales: Benmebarek, Sabrina, Boudraa, Mhamed, Bouacida, Sofiane, Merazig, Hocine, Dénès, George
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914061/
https://www.ncbi.nlm.nih.gov/pubmed/24526954
http://dx.doi.org/10.1107/S160053681303417X
Descripción
Sumario:In the title compound, [ZnCl(2)(C(6)H(8)N(2)O(2)S)(2)], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra­hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn—Cl = 2.2288 (16) Å and Zn—N = 2.060 (5) Å]. The dihedral angle between the benzene rings is 67.1 (3)°. The crystal packing can be describe as layers in a zigzag arrangement parallel to (001). The amine H atoms act as donor atoms and participate in inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds, forming a three-dimensional network.

Ejemplares similares