Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc

In the title compound, [ZnCl(2)(C(6)H(8)N(2)O(2)S)(2)], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra­hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn—Cl = 2.2288 (16) Å and Zn—N...

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Autores principales: Benmebarek, Sabrina, Boudraa, Mhamed, Bouacida, Sofiane, Merazig, Hocine, Dénès, George
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914061/
https://www.ncbi.nlm.nih.gov/pubmed/24526954
http://dx.doi.org/10.1107/S160053681303417X
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author Benmebarek, Sabrina
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Dénès, George
author_facet Benmebarek, Sabrina
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Dénès, George
author_sort Benmebarek, Sabrina
collection PubMed
description In the title compound, [ZnCl(2)(C(6)H(8)N(2)O(2)S)(2)], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra­hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn—Cl = 2.2288 (16) Å and Zn—N = 2.060 (5) Å]. The dihedral angle between the benzene rings is 67.1 (3)°. The crystal packing can be describe as layers in a zigzag arrangement parallel to (001). The amine H atoms act as donor atoms and participate in inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-39140612014-02-13 Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc Benmebarek, Sabrina Boudraa, Mhamed Bouacida, Sofiane Merazig, Hocine Dénès, George Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(6)H(8)N(2)O(2)S)(2)], the Zn(II) ion lies on a twofold rotation axis and has a slightly distorted tetra­hedral coordination geometry, involving two Cl atoms and two N atoms from the amino groups attached directly to the benzene rings [Zn—Cl = 2.2288 (16) Å and Zn—N = 2.060 (5) Å]. The dihedral angle between the benzene rings is 67.1 (3)°. The crystal packing can be describe as layers in a zigzag arrangement parallel to (001). The amine H atoms act as donor atoms and participate in inter­molecular N—H⋯O and N—H⋯Cl hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-12-24 /pmc/articles/PMC3914061/ /pubmed/24526954 http://dx.doi.org/10.1107/S160053681303417X Text en © Benmebarek et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benmebarek, Sabrina
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Dénès, George
Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title_full Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title_fullStr Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title_full_unstemmed Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title_short Bis(4-amino­benzene­sulfonamide-κN (4))di­chlorido­zinc
title_sort bis(4-amino­benzene­sulfonamide-κn (4))di­chlorido­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914061/
https://www.ncbi.nlm.nih.gov/pubmed/24526954
http://dx.doi.org/10.1107/S160053681303417X
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