Dimethyl 2-[2-(2,4,6-tri­chloro­phen­yl)hydrazin-1-yl­idene]butane­dioate

In the title compound, C(12)H(11)Cl(3)N(2)O(4), the dihedral angle between the aromatic ring and the hydrazine (NH—N=C) grouping is 52.2 (3)°. The butanedioate groups exhibit planar conformations. An intra­molecular N—H⋯O hydrogen bond links the N—H group of the hydrazine to one of the meth­oxy grou...

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Detalles Bibliográficos
Autores principales: Usha, M. K., Shetty, Shobhitha, Kalluraya, B., Kant, Rajni, Gupta, Vivek K., Revannasiddaiah, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914063/
https://www.ncbi.nlm.nih.gov/pubmed/24526964
http://dx.doi.org/10.1107/S160053681303242X
Descripción
Sumario:In the title compound, C(12)H(11)Cl(3)N(2)O(4), the dihedral angle between the aromatic ring and the hydrazine (NH—N=C) grouping is 52.2 (3)°. The butanedioate groups exhibit planar conformations. An intra­molecular N—H⋯O hydrogen bond links the N—H group of the hydrazine to one of the meth­oxy groups of the butane­dioate moiety. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and π–π inter­actions are also observed [centroid–centroid separation = 3.535 (1) Å].

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