4-Nitro­phenyl­hydrazinium picrate monohydrate

In the crystal structure of the title compound, C(6)H(8)N(3)O(2) (+)·C(6)H(2)N(3)O(7) (−)·H(2)O, N—H⋯O and O—H⋯O hydrogen bonds link the components into a two-dimensional network parallel to (010). In addition, there are pairs of weak inversion-related C—H⋯O hydrogen bonds within the two-dimensional...

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Detalles Bibliográficos
Autores principales: Cai, Hong-lan, Liu, Bing, Qiao, Qing-an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914065/
https://www.ncbi.nlm.nih.gov/pubmed/24526966
http://dx.doi.org/10.1107/S1600536813032479
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author Cai, Hong-lan
Liu, Bing
Qiao, Qing-an
author_facet Cai, Hong-lan
Liu, Bing
Qiao, Qing-an
author_sort Cai, Hong-lan
collection PubMed
description In the crystal structure of the title compound, C(6)H(8)N(3)O(2) (+)·C(6)H(2)N(3)O(7) (−)·H(2)O, N—H⋯O and O—H⋯O hydrogen bonds link the components into a two-dimensional network parallel to (010). In addition, there are pairs of weak inversion-related C—H⋯O hydrogen bonds within the two-dimensional network. The three nitro groups are twisted by 1.6 (3), 7.8 (3) and 12.1 (3)° from the ring plane in the anion, while in the cation, the nitro group makes a dihedral angle of 4.6 (2)° with the ring.
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spelling pubmed-39140652014-02-13 4-Nitro­phenyl­hydrazinium picrate monohydrate Cai, Hong-lan Liu, Bing Qiao, Qing-an Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(6)H(8)N(3)O(2) (+)·C(6)H(2)N(3)O(7) (−)·H(2)O, N—H⋯O and O—H⋯O hydrogen bonds link the components into a two-dimensional network parallel to (010). In addition, there are pairs of weak inversion-related C—H⋯O hydrogen bonds within the two-dimensional network. The three nitro groups are twisted by 1.6 (3), 7.8 (3) and 12.1 (3)° from the ring plane in the anion, while in the cation, the nitro group makes a dihedral angle of 4.6 (2)° with the ring. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914065/ /pubmed/24526966 http://dx.doi.org/10.1107/S1600536813032479 Text en © Cai et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cai, Hong-lan
Liu, Bing
Qiao, Qing-an
4-Nitro­phenyl­hydrazinium picrate monohydrate
title 4-Nitro­phenyl­hydrazinium picrate monohydrate
title_full 4-Nitro­phenyl­hydrazinium picrate monohydrate
title_fullStr 4-Nitro­phenyl­hydrazinium picrate monohydrate
title_full_unstemmed 4-Nitro­phenyl­hydrazinium picrate monohydrate
title_short 4-Nitro­phenyl­hydrazinium picrate monohydrate
title_sort 4-nitro­phenyl­hydrazinium picrate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914065/
https://www.ncbi.nlm.nih.gov/pubmed/24526966
http://dx.doi.org/10.1107/S1600536813032479
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AT liubing 4nitrophenylhydraziniumpicratemonohydrate
AT qiaoqingan 4nitrophenylhydraziniumpicratemonohydrate

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