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1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone

In the title compound, C(11)H(10)O(3), there is an intra­molecular O—H⋯O hydrogen bond generating an S(6) ring motif. The O atom of the hy­droxy group deviates by 0.0200 (1) Å from the benzene ring to which it is attached. The propyne group is almost linear, the C—C C angle being 177.83 (15)°, and i...

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Autores principales: Selvarani, V., Neelakantan, M. A., Srinivasan, T., Velmurugan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914071/
https://www.ncbi.nlm.nih.gov/pubmed/24526972
http://dx.doi.org/10.1107/S1600536813032613
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author Selvarani, V.
Neelakantan, M. A.
Srinivasan, T.
Velmurugan, D.
author_facet Selvarani, V.
Neelakantan, M. A.
Srinivasan, T.
Velmurugan, D.
author_sort Selvarani, V.
collection PubMed
description In the title compound, C(11)H(10)O(3), there is an intra­molecular O—H⋯O hydrogen bond generating an S(6) ring motif. The O atom of the hy­droxy group deviates by 0.0200 (1) Å from the benzene ring to which it is attached. The propyne group is almost linear, the C—C C angle being 177.83 (15)°, and is almost coplanar with the benzene ring; the C—C—O—C torsion angle being only −1.1 (2)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming infinite C(11) chains running parallel to [103]. These chains are linked by a pair of C—H⋯O hydrogen bonds, enclosing R (2) (2)(8) inversion dimers, forming a corrugated two-dimensional network lying parallel to (103).
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spelling pubmed-39140712014-02-13 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone Selvarani, V. Neelakantan, M. A. Srinivasan, T. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(10)O(3), there is an intra­molecular O—H⋯O hydrogen bond generating an S(6) ring motif. The O atom of the hy­droxy group deviates by 0.0200 (1) Å from the benzene ring to which it is attached. The propyne group is almost linear, the C—C C angle being 177.83 (15)°, and is almost coplanar with the benzene ring; the C—C—O—C torsion angle being only −1.1 (2)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming infinite C(11) chains running parallel to [103]. These chains are linked by a pair of C—H⋯O hydrogen bonds, enclosing R (2) (2)(8) inversion dimers, forming a corrugated two-dimensional network lying parallel to (103). International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914071/ /pubmed/24526972 http://dx.doi.org/10.1107/S1600536813032613 Text en © Selvarani et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvarani, V.
Neelakantan, M. A.
Srinivasan, T.
Velmurugan, D.
1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title_full 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title_fullStr 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title_full_unstemmed 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title_short 1-[2-Hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
title_sort 1-[2-hy­droxy-4-(prop-2-yn-1-yl­oxy)phen­yl]ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914071/
https://www.ncbi.nlm.nih.gov/pubmed/24526972
http://dx.doi.org/10.1107/S1600536813032613
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