2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide

In the title compound, C(12)H(14)Cl(2)N(2)O(2)S, the mol­ecule adopts a cis conformation with respect to the di­chloro­benzoyl group against the thiono group about the C—N bond. However, the di­chloro­benzene group and the thio­urea moiety are twisted by 75.41 (8)°. An intra­molecular N—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M, Sapari, Suhaila, Hasbullah, Siti Aishah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914078/
https://www.ncbi.nlm.nih.gov/pubmed/24526980
http://dx.doi.org/10.1107/S1600536813032881
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author Yamin, Bohari M
Sapari, Suhaila
Hasbullah, Siti Aishah
author_facet Yamin, Bohari M
Sapari, Suhaila
Hasbullah, Siti Aishah
author_sort Yamin, Bohari M
collection PubMed
description In the title compound, C(12)H(14)Cl(2)N(2)O(2)S, the mol­ecule adopts a cis conformation with respect to the di­chloro­benzoyl group against the thiono group about the C—N bond. However, the di­chloro­benzene group and the thio­urea moiety are twisted by 75.41 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O—H⋯S and O—H⋯O hydrogen bonds link the molecules, forming chains along the b-axis direction.
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spelling pubmed-39140782014-02-13 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide Yamin, Bohari M Sapari, Suhaila Hasbullah, Siti Aishah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(14)Cl(2)N(2)O(2)S, the mol­ecule adopts a cis conformation with respect to the di­chloro­benzoyl group against the thiono group about the C—N bond. However, the di­chloro­benzene group and the thio­urea moiety are twisted by 75.41 (8)°. An intra­molecular N—H⋯O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O—H⋯S and O—H⋯O hydrogen bonds link the molecules, forming chains along the b-axis direction. International Union of Crystallography 2013-12-11 /pmc/articles/PMC3914078/ /pubmed/24526980 http://dx.doi.org/10.1107/S1600536813032881 Text en © Yamin et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M
Sapari, Suhaila
Hasbullah, Siti Aishah
2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title_full 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title_fullStr 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title_full_unstemmed 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title_short 2,4-Di­chloro-N-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
title_sort 2,4-di­chloro-n-[eth­yl(2-hy­droxy­eth­yl)carbamo­thio­yl]benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914078/
https://www.ncbi.nlm.nih.gov/pubmed/24526980
http://dx.doi.org/10.1107/S1600536813032881
work_keys_str_mv AT yaminboharim 24dichloronethyl2hydroxyethylcarbamothioylbenzamide
AT saparisuhaila 24dichloronethyl2hydroxyethylcarbamothioylbenzamide
AT hasbullahsitiaishah 24dichloronethyl2hydroxyethylcarbamothioylbenzamide

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