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6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]

In the title compound, C(39)H(38)N(4)O(8), the quinoxaline and indene subunits are essentially planar, with maximum deviations of 0.071 (2) and 0.009 (2) Å, respectively. The indeno­quinoxaline system forms a dihedral angle of 72.81 (3)° with the chromenopyrrolizine system. The two dioxolane rings,...

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Autores principales: Anuradha, T., Naga Siva Rao, J., Seshadri, P. R., Raghunathan, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914082/
https://www.ncbi.nlm.nih.gov/pubmed/24526984
http://dx.doi.org/10.1107/S1600536813032467
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author Anuradha, T.
Naga Siva Rao, J.
Seshadri, P. R.
Raghunathan, R.
author_facet Anuradha, T.
Naga Siva Rao, J.
Seshadri, P. R.
Raghunathan, R.
author_sort Anuradha, T.
collection PubMed
description In the title compound, C(39)H(38)N(4)O(8), the quinoxaline and indene subunits are essentially planar, with maximum deviations of 0.071 (2) and 0.009 (2) Å, respectively. The indeno­quinoxaline system forms a dihedral angle of 72.81 (3)° with the chromenopyrrolizine system. The two dioxolane rings, as well as the pyran ring of the chromeno group and the terminal pyrrolizine, each adopt an envelope conformation with O and C as flap atoms. The central pyrrolizine ring adopts a twisted conformation. Intra­molecular C—H⋯O and C—H⋯N hydrogen bonds occur. The crystal structure exhibits C—H⋯O hydrogen bonds, and is further stablized by C—H⋯π inter­actions, forming a two-dimensional network along the bc plane.
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spelling pubmed-39140822014-02-13 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline] Anuradha, T. Naga Siva Rao, J. Seshadri, P. R. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(39)H(38)N(4)O(8), the quinoxaline and indene subunits are essentially planar, with maximum deviations of 0.071 (2) and 0.009 (2) Å, respectively. The indeno­quinoxaline system forms a dihedral angle of 72.81 (3)° with the chromenopyrrolizine system. The two dioxolane rings, as well as the pyran ring of the chromeno group and the terminal pyrrolizine, each adopt an envelope conformation with O and C as flap atoms. The central pyrrolizine ring adopts a twisted conformation. Intra­molecular C—H⋯O and C—H⋯N hydrogen bonds occur. The crystal structure exhibits C—H⋯O hydrogen bonds, and is further stablized by C—H⋯π inter­actions, forming a two-dimensional network along the bc plane. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914082/ /pubmed/24526984 http://dx.doi.org/10.1107/S1600536813032467 Text en © Anuradha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, T.
Naga Siva Rao, J.
Seshadri, P. R.
Raghunathan, R.
6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title_full 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title_fullStr 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title_full_unstemmed 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title_short 6a-Nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3aH-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6H-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
title_sort 6a-nitro-6-(2,2,7,7-tetra­methyl­tetra­hydro-3ah-bis­[1,3]dioxolo[4,5-b:4′,5′-d]pyran-5-yl)-6a,6b,7,8,9,11a-hexa­hydro-6h-spiro­[chromeno[3,4-a]pyrrolizine-11,11′-indeno­[1,2-b]quinoxaline]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914082/
https://www.ncbi.nlm.nih.gov/pubmed/24526984
http://dx.doi.org/10.1107/S1600536813032467
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