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4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol

In the title Schiff base mol­ecule, C(13)H(9)ClFNO, the benzene rings are twisted slightly with respect to each other, making a dihedral angle of 7.92 (2)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, an infinite chain is formed along the c-axis direction by π–π stacking inter­act...

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Detalles Bibliográficos
Autor principal: Feng, Tian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914085/
https://www.ncbi.nlm.nih.gov/pubmed/24526988
http://dx.doi.org/10.1107/S1600536813033278
Descripción
Sumario:In the title Schiff base mol­ecule, C(13)H(9)ClFNO, the benzene rings are twisted slightly with respect to each other, making a dihedral angle of 7.92 (2)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, an infinite chain is formed along the c-axis direction by π–π stacking inter­actions between the phenyl rings and the six-membered hydrogen-bonded ring of neighboring Schiff base ligands [centroid–centroid distances of 3.698 (2) and 3.660 (3) Å]. Neighboring chains are linked into a three-dimensional supra­molecular structure by C—H⋯O and C—H⋯F hydrogen bonds.