4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol

In the title Schiff base mol­ecule, C(13)H(9)ClFNO, the benzene rings are twisted slightly with respect to each other, making a dihedral angle of 7.92 (2)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, an infinite chain is formed along the c-axis direction by π–π stacking inter­act...

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Detalles Bibliográficos
Autor principal: Feng, Tian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914085/
https://www.ncbi.nlm.nih.gov/pubmed/24526988
http://dx.doi.org/10.1107/S1600536813033278
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author Feng, Tian-Jun
author_facet Feng, Tian-Jun
author_sort Feng, Tian-Jun
collection PubMed
description In the title Schiff base mol­ecule, C(13)H(9)ClFNO, the benzene rings are twisted slightly with respect to each other, making a dihedral angle of 7.92 (2)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, an infinite chain is formed along the c-axis direction by π–π stacking inter­actions between the phenyl rings and the six-membered hydrogen-bonded ring of neighboring Schiff base ligands [centroid–centroid distances of 3.698 (2) and 3.660 (3) Å]. Neighboring chains are linked into a three-dimensional supra­molecular structure by C—H⋯O and C—H⋯F hydrogen bonds.
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spelling pubmed-39140852014-02-13 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol Feng, Tian-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base mol­ecule, C(13)H(9)ClFNO, the benzene rings are twisted slightly with respect to each other, making a dihedral angle of 7.92 (2)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, an infinite chain is formed along the c-axis direction by π–π stacking inter­actions between the phenyl rings and the six-membered hydrogen-bonded ring of neighboring Schiff base ligands [centroid–centroid distances of 3.698 (2) and 3.660 (3) Å]. Neighboring chains are linked into a three-dimensional supra­molecular structure by C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914085/ /pubmed/24526988 http://dx.doi.org/10.1107/S1600536813033278 Text en © Tian-Jun Feng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Feng, Tian-Jun
4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title_full 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title_fullStr 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title_full_unstemmed 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title_short 4-Chloro-2-[(E)-(4-fluoro­phen­yl)imino­meth­yl]phenol
title_sort 4-chloro-2-[(e)-(4-fluoro­phen­yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914085/
https://www.ncbi.nlm.nih.gov/pubmed/24526988
http://dx.doi.org/10.1107/S1600536813033278
work_keys_str_mv AT fengtianjun 4chloro2e4fluorophenyliminomethylphenol

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