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2-(3-Cyano-4-{3-[1-(2-hydroxyethyl)-3,3-dimethyl-1,3-dihydroindol-2-ylidene]prop-2-enyl}-5,5-dimethyl-5H-furan-2-ylidene)malononitrile
The title compound, C(25)H(24)N(4)O(2), adopts a cisoid configuration and has twofold orientational disorder of the 2-hydroxyethyl group. The molecule is twisted from planarity so that the dihedral angle between the terminating indol-2-ylidene and the furan-2-ylidene moiety mean planes is 12.75...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914086/ https://www.ncbi.nlm.nih.gov/pubmed/24526989 http://dx.doi.org/10.1107/S1600536813033242 |
Sumario: | The title compound, C(25)H(24)N(4)O(2), adopts a cisoid configuration and has twofold orientational disorder of the 2-hydroxyethyl group. The molecule is twisted from planarity so that the dihedral angle between the terminating indol-2-ylidene and the furan-2-ylidene moiety mean planes is 12.75 (7)°. Conformational disorder occurs at the indol-2-ylidene N atom, which results in two orientations for the hydroxyethyl group [occupancy ratio = 0.896 (2):0.104 (2)], and the hydroxy O atom of the 2-hydroxyethyl group is located over three sites [occupancy ratio = 0.548 (2):0.348 (2):0.104 (2)]. An intramolecular C—H⋯O hydrogen bond involving the lowest occupancy hydroxy O atom is observed. In the crystal, the molecules pack in parallel dimeric sheets about centres of symmetry, utilizing O—H⋯N(cyano), C—H⋯N(cyano) and O—H⋯O hydrogen bonds, in two sets parallel to (02-1) and (021) planes. |
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