5,5,7,12,12,14-Hexamethyl-1,8-bis­(4-nitro­benz­yl)-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne

The asymmetric unit of the title compound, C(30)H(46)N(6)O(4), contains one half-mol­ecule. The C(benzene)—C(CH(2))—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitro­benzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by...

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Detalles Bibliográficos
Autores principales: Gayathri, K., Sathya, S., Usha, G., Ramanjaneya Reddy, G., Balasubramanian, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914089/
https://www.ncbi.nlm.nih.gov/pubmed/24526993
http://dx.doi.org/10.1107/S1600536813031164
Descripción
Sumario:The asymmetric unit of the title compound, C(30)H(46)N(6)O(4), contains one half-mol­ecule. The C(benzene)—C(CH(2))—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitro­benzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by intra­molecular N—H⋯N hydrogen bonds.

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