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5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane
The asymmetric unit of the title compound, C(30)H(46)N(6)O(4), contains one half-molecule. The C(benzene)—C(CH(2))—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitrobenzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914089/ https://www.ncbi.nlm.nih.gov/pubmed/24526993 http://dx.doi.org/10.1107/S1600536813031164 |
| _version_ | 1782302342301876224 |
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| author | Gayathri, K. Sathya, S. Usha, G. Ramanjaneya Reddy, G. Balasubramanian, S. |
| author_facet | Gayathri, K. Sathya, S. Usha, G. Ramanjaneya Reddy, G. Balasubramanian, S. |
| author_sort | Gayathri, K. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, C(30)H(46)N(6)O(4), contains one half-molecule. The C(benzene)—C(CH(2))—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitrobenzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by intramolecular N—H⋯N hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3914089 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39140892014-02-13 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane Gayathri, K. Sathya, S. Usha, G. Ramanjaneya Reddy, G. Balasubramanian, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(30)H(46)N(6)O(4), contains one half-molecule. The C(benzene)—C(CH(2))—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitrobenzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by intramolecular N—H⋯N hydrogen bonds. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914089/ /pubmed/24526993 http://dx.doi.org/10.1107/S1600536813031164 Text en © Gayathri et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Gayathri, K. Sathya, S. Usha, G. Ramanjaneya Reddy, G. Balasubramanian, S. 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title | 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title_full | 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title_fullStr | 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title_full_unstemmed | 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title_short | 5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| title_sort | 5,5,7,12,12,14-hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914089/ https://www.ncbi.nlm.nih.gov/pubmed/24526993 http://dx.doi.org/10.1107/S1600536813031164 |
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