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2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate

In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)°...

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Autores principales: Srinivasan, N., Thiruvalluvar, A., Rosepriya, S., Prakash, S. M., Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914093/
https://www.ncbi.nlm.nih.gov/pubmed/24526997
http://dx.doi.org/10.1107/S160053681303331X
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author Srinivasan, N.
Thiruvalluvar, A.
Rosepriya, S.
Prakash, S. M.
Butcher, R. J.
author_facet Srinivasan, N.
Thiruvalluvar, A.
Rosepriya, S.
Prakash, S. M.
Butcher, R. J.
author_sort Srinivasan, N.
collection PubMed
description In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)° with the phenyl ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, seven weak C—H⋯π inter­actions involving the fused ring system, the benzene solvent mol­ecule, the imidazole phenyl rings are observed, leading to a three-dimensional architecture.
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spelling pubmed-39140932014-02-13 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate Srinivasan, N. Thiruvalluvar, A. Rosepriya, S. Prakash, S. M. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)° with the phenyl ring. An intra­molecular C—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, seven weak C—H⋯π inter­actions involving the fused ring system, the benzene solvent mol­ecule, the imidazole phenyl rings are observed, leading to a three-dimensional architecture. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914093/ /pubmed/24526997 http://dx.doi.org/10.1107/S160053681303331X Text en © Srinivasan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Srinivasan, N.
Thiruvalluvar, A.
Rosepriya, S.
Prakash, S. M.
Butcher, R. J.
2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title_full 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title_fullStr 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title_full_unstemmed 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title_short 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimid­azole benzene hemisolvate
title_sort 2-(naphthalen-1-yl)-1-phenyl-1h-benzimid­azole benzene hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914093/
https://www.ncbi.nlm.nih.gov/pubmed/24526997
http://dx.doi.org/10.1107/S160053681303331X
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