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2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate
In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)°...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914093/ https://www.ncbi.nlm.nih.gov/pubmed/24526997 http://dx.doi.org/10.1107/S160053681303331X |
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author | Srinivasan, N. Thiruvalluvar, A. Rosepriya, S. Prakash, S. M. Butcher, R. J. |
author_facet | Srinivasan, N. Thiruvalluvar, A. Rosepriya, S. Prakash, S. M. Butcher, R. J. |
author_sort | Srinivasan, N. |
collection | PubMed |
description | In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)° with the phenyl ring. An intramolecular C—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, seven weak C—H⋯π interactions involving the fused ring system, the benzene solvent molecule, the imidazole phenyl rings are observed, leading to a three-dimensional architecture. |
format | Online Article Text |
id | pubmed-3914093 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140932014-02-13 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate Srinivasan, N. Thiruvalluvar, A. Rosepriya, S. Prakash, S. M. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(16)N(2)·0.5C(6)H(6), the benzimidazole unit [maximum deviation = 0.0258 (6) Å] and the naphthalene ring system [maximum deviation = 0.0254 (6) Å] are both essentially planar and make a dihedral angle of 61.955 (17)°. The imidazole ring makes dihedral angle of 61.73 (4)° with the phenyl ring. An intramolecular C—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, seven weak C—H⋯π interactions involving the fused ring system, the benzene solvent molecule, the imidazole phenyl rings are observed, leading to a three-dimensional architecture. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914093/ /pubmed/24526997 http://dx.doi.org/10.1107/S160053681303331X Text en © Srinivasan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Srinivasan, N. Thiruvalluvar, A. Rosepriya, S. Prakash, S. M. Butcher, R. J. 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title | 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title_full | 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title_fullStr | 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title_full_unstemmed | 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title_short | 2-(Naphthalen-1-yl)-1-phenyl-1H-benzimidazole benzene hemisolvate |
title_sort | 2-(naphthalen-1-yl)-1-phenyl-1h-benzimidazole benzene hemisolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914093/ https://www.ncbi.nlm.nih.gov/pubmed/24526997 http://dx.doi.org/10.1107/S160053681303331X |
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