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(E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
There are two independent molecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each molecule adopts a trans configuration with respect to the methylidene C=N bond and is twisted with a dihedral angle between...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914096/ https://www.ncbi.nlm.nih.gov/pubmed/24527001 http://dx.doi.org/10.1107/S1600536813032996 |
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author | Kaewmanee, Narissara Chantrapromma, Suchada Boonnak, Nawong Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Kaewmanee, Narissara Chantrapromma, Suchada Boonnak, Nawong Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Kaewmanee, Narissara |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each molecule adopts a trans configuration with respect to the methylidene C=N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)° in one molecule and 83.53 (7)° in the other. All methoxy groups are approximately coplanar with the attached benzene rings, with C(methyl)—O—C—C torsion angles ranging from −6.7 (2) to 5.07 (19)°. In the crystal, independent molecules are linked together by O—H⋯N and O—H⋯O hydrogen bonds and a π–π interaction [centroid–centroid distance of 3.6030 (9) Å], forming a dimer. The dimers are further linked by weak C—H⋯O interactions and another π–π interaction [centroid–centroid distance of 3.9452 (9) Å] into layers lying parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3914096 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140962014-02-13 (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol Kaewmanee, Narissara Chantrapromma, Suchada Boonnak, Nawong Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each molecule adopts a trans configuration with respect to the methylidene C=N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)° in one molecule and 83.53 (7)° in the other. All methoxy groups are approximately coplanar with the attached benzene rings, with C(methyl)—O—C—C torsion angles ranging from −6.7 (2) to 5.07 (19)°. In the crystal, independent molecules are linked together by O—H⋯N and O—H⋯O hydrogen bonds and a π–π interaction [centroid–centroid distance of 3.6030 (9) Å], forming a dimer. The dimers are further linked by weak C—H⋯O interactions and another π–π interaction [centroid–centroid distance of 3.9452 (9) Å] into layers lying parallel to the ab plane. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914096/ /pubmed/24527001 http://dx.doi.org/10.1107/S1600536813032996 Text en © Kaewmanee et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kaewmanee, Narissara Chantrapromma, Suchada Boonnak, Nawong Quah, Ching Kheng Fun, Hoong-Kun (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol |
title | (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
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title_full | (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
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title_fullStr | (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
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title_full_unstemmed | (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
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title_short | (E)-2-[(2,4,6-Trimethoxybenzylidene)amino]phenol
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title_sort | (e)-2-[(2,4,6-trimethoxybenzylidene)amino]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914096/ https://www.ncbi.nlm.nih.gov/pubmed/24527001 http://dx.doi.org/10.1107/S1600536813032996 |
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