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(E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol

There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each mol­ecule adopts a trans configuration with respect to the methyl­idene C=N bond and is twisted with a dihedral angle between...

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Autores principales: Kaewmanee, Narissara, Chantrapromma, Suchada, Boonnak, Nawong, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914096/
https://www.ncbi.nlm.nih.gov/pubmed/24527001
http://dx.doi.org/10.1107/S1600536813032996
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author Kaewmanee, Narissara
Chantrapromma, Suchada
Boonnak, Nawong
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Kaewmanee, Narissara
Chantrapromma, Suchada
Boonnak, Nawong
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Kaewmanee, Narissara
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each mol­ecule adopts a trans configuration with respect to the methyl­idene C=N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)° in one mol­ecule and 83.53 (7)° in the other. All meth­oxy groups are approximately coplanar with the attached benzene rings, with C(meth­yl)—O—C—C torsion angles ranging from −6.7 (2) to 5.07 (19)°. In the crystal, independent mol­ecules are linked together by O—H⋯N and O—H⋯O hydrogen bonds and a π–π inter­action [centroid–centroid distance of 3.6030 (9) Å], forming a dimer. The dimers are further linked by weak C—H⋯O inter­actions and another π–π inter­action [centroid–centroid distance of 3.9452 (9) Å] into layers lying parallel to the ab plane.
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spelling pubmed-39140962014-02-13 (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol Kaewmanee, Narissara Chantrapromma, Suchada Boonnak, Nawong Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(16)H(17)NO(4), with similar conformations but some differences in their bond angles. Each mol­ecule adopts a trans configuration with respect to the methyl­idene C=N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)° in one mol­ecule and 83.53 (7)° in the other. All meth­oxy groups are approximately coplanar with the attached benzene rings, with C(meth­yl)—O—C—C torsion angles ranging from −6.7 (2) to 5.07 (19)°. In the crystal, independent mol­ecules are linked together by O—H⋯N and O—H⋯O hydrogen bonds and a π–π inter­action [centroid–centroid distance of 3.6030 (9) Å], forming a dimer. The dimers are further linked by weak C—H⋯O inter­actions and another π–π inter­action [centroid–centroid distance of 3.9452 (9) Å] into layers lying parallel to the ab plane. International Union of Crystallography 2013-12-14 /pmc/articles/PMC3914096/ /pubmed/24527001 http://dx.doi.org/10.1107/S1600536813032996 Text en © Kaewmanee et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kaewmanee, Narissara
Chantrapromma, Suchada
Boonnak, Nawong
Quah, Ching Kheng
Fun, Hoong-Kun
(E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title_full (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title_fullStr (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title_full_unstemmed (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title_short (E)-2-[(2,4,6-Tri­meth­oxy­benzyl­idene)amino]­phenol
title_sort (e)-2-[(2,4,6-tri­meth­oxy­benzyl­idene)amino]­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914096/
https://www.ncbi.nlm.nih.gov/pubmed/24527001
http://dx.doi.org/10.1107/S1600536813032996
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