N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

In the title compound, 2C(11)H(18)N(+)·2PF(6) (−)·C(12)H(24)O(6), the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C—H⋯O hydrogen bonds. The cations and anions are further linked via N—H⋯F and C—H⋯F hydrogen bond...

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Detalles Bibliográficos
Autores principales: Chang, Yi Qi, Zhang, Yuan, Lian, Huo Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914100/
https://www.ncbi.nlm.nih.gov/pubmed/24527005
http://dx.doi.org/10.1107/S1600536813033734
Descripción
Sumario:In the title compound, 2C(11)H(18)N(+)·2PF(6) (−)·C(12)H(24)O(6), the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C—H⋯O hydrogen bonds. The cations and anions are further linked via N—H⋯F and C—H⋯F hydrogen bonds, leading to a sandwich structure .

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