N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)

In the title compound, 2C(11)H(18)N(+)·2PF(6) (−)·C(12)H(24)O(6), the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C—H⋯O hydrogen bonds. The cations and anions are further linked via N—H⋯F and C—H⋯F hydrogen bond...

Descripción completa

Detalles Bibliográficos
Autores principales: Chang, Yi Qi, Zhang, Yuan, Lian, Huo Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914100/
https://www.ncbi.nlm.nih.gov/pubmed/24527005
http://dx.doi.org/10.1107/S1600536813033734
_version_ 1782302344777564160
author Chang, Yi Qi
Zhang, Yuan
Lian, Huo Lin
author_facet Chang, Yi Qi
Zhang, Yuan
Lian, Huo Lin
author_sort Chang, Yi Qi
collection PubMed
description In the title compound, 2C(11)H(18)N(+)·2PF(6) (−)·C(12)H(24)O(6), the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C—H⋯O hydrogen bonds. The cations and anions are further linked via N—H⋯F and C—H⋯F hydrogen bonds, leading to a sandwich structure .
format Online
Article
Text
id pubmed-3914100
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39141002014-02-13 N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1) Chang, Yi Qi Zhang, Yuan Lian, Huo Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(11)H(18)N(+)·2PF(6) (−)·C(12)H(24)O(6), the 18-crown-6 mol­ecule has crystallographically imposed inversion symmetry. In the crystal, it inter­acts with the cation through weak C—H⋯O hydrogen bonds. The cations and anions are further linked via N—H⋯F and C—H⋯F hydrogen bonds, leading to a sandwich structure . International Union of Crystallography 2013-12-18 /pmc/articles/PMC3914100/ /pubmed/24527005 http://dx.doi.org/10.1107/S1600536813033734 Text en © Chang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chang, Yi Qi
Zhang, Yuan
Lian, Huo Lin
N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title_full N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title_fullStr N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title_full_unstemmed N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title_short N,N,2,4,6-Penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
title_sort n,n,2,4,6-penta­methyl­anilinium hexa­fluoro­phosphate–1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane (2/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914100/
https://www.ncbi.nlm.nih.gov/pubmed/24527005
http://dx.doi.org/10.1107/S1600536813033734
work_keys_str_mv AT changyiqi nn246pentamethylaniliniumhexafluorophosphate147101316hexaoxacyclooctadecane21
AT zhangyuan nn246pentamethylaniliniumhexafluorophosphate147101316hexaoxacyclooctadecane21
AT lianhuolin nn246pentamethylaniliniumhexafluorophosphate147101316hexaoxacyclooctadecane21

Ejemplares similares