(1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid

The title compound, C(10)H(12)O(8), a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclo­hexane ring adopts a chair conformation. Two crystallographycally independent carb­oxy­lic acid groups on...

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Autores principales: Uchida, Akira, Hasegawa, Masatoshi, Yamaguchi, Shinya, Takezawa, Eiichiro, Ishikawa, Atsushi, Kagayama, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914102/
https://www.ncbi.nlm.nih.gov/pubmed/24527007
http://dx.doi.org/10.1107/S1600536813033795
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author Uchida, Akira
Hasegawa, Masatoshi
Yamaguchi, Shinya
Takezawa, Eiichiro
Ishikawa, Atsushi
Kagayama, Takashi
author_facet Uchida, Akira
Hasegawa, Masatoshi
Yamaguchi, Shinya
Takezawa, Eiichiro
Ishikawa, Atsushi
Kagayama, Takashi
author_sort Uchida, Akira
collection PubMed
description The title compound, C(10)H(12)O(8), a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclo­hexane ring adopts a chair conformation. Two crystallographycally independent carb­oxy­lic acid groups on adjacent C atoms are in equatorial positions, resulting in a mutually trans conformation. In the crystal, O—H⋯O hydrogen bonds around an inversion centre and a threefold rotoinversion axis, respectively, form an inversion dimer with an R (2) (2)(8) motif and a trimer with an R (3) (3)(12) motif.
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spelling pubmed-39141022014-02-13 (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid Uchida, Akira Hasegawa, Masatoshi Yamaguchi, Shinya Takezawa, Eiichiro Ishikawa, Atsushi Kagayama, Takashi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)O(8), a prospective raw material for colourless polyimides which are applied to electronic and microelectronic devices, lies about an inversion centre and the cyclo­hexane ring adopts a chair conformation. Two crystallographycally independent carb­oxy­lic acid groups on adjacent C atoms are in equatorial positions, resulting in a mutually trans conformation. In the crystal, O—H⋯O hydrogen bonds around an inversion centre and a threefold rotoinversion axis, respectively, form an inversion dimer with an R (2) (2)(8) motif and a trimer with an R (3) (3)(12) motif. International Union of Crystallography 2013-12-21 /pmc/articles/PMC3914102/ /pubmed/24527007 http://dx.doi.org/10.1107/S1600536813033795 Text en © Uchida et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Uchida, Akira
Hasegawa, Masatoshi
Yamaguchi, Shinya
Takezawa, Eiichiro
Ishikawa, Atsushi
Kagayama, Takashi
(1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title_full (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title_fullStr (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title_full_unstemmed (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title_short (1S*,2S*,4R*,5R*)-Cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
title_sort (1s*,2s*,4r*,5r*)-cyclo­hexane-1,2,4,5-tetra­carb­oxy­lic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914102/
https://www.ncbi.nlm.nih.gov/pubmed/24527007
http://dx.doi.org/10.1107/S1600536813033795
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