5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate

In the title compound, C(18)H(13)ClN(2)OS·CH(3)OH, the dihedral angle between the benzimidazole group and the naphth­yloxy moiety [82.89 (5)°] very near to orthogonality. The H atom in the five-membered ring is disordered with equal occupancies at the two N atoms and the H atom of the methano­lic hy...

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Detalles Bibliográficos
Autores principales: Flores-Ramos, Miguel, Castillo, Rafael, Hernández-Campos, Alicia, Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914104/
https://www.ncbi.nlm.nih.gov/pubmed/24527009
http://dx.doi.org/10.1107/S1600536813033709
Descripción
Sumario:In the title compound, C(18)H(13)ClN(2)OS·CH(3)OH, the dihedral angle between the benzimidazole group and the naphth­yloxy moiety [82.89 (5)°] very near to orthogonality. The H atom in the five-membered ring is disordered with equal occupancies at the two N atoms and the H atom of the methano­lic hy­droxy group is disordered with equal occupancies over two sites at the O atom. The methanol mol­ecule acts as a hydrogen-bond acceptor for the amino H atom and donates a hydrogen bond to the nonprotonated ring N atom. As a result, chains are formed running along the a axis.

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