5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate

In the title compound, C(18)H(13)ClN(2)OS·CH(3)OH, the dihedral angle between the benzimidazole group and the naphth­yloxy moiety [82.89 (5)°] very near to orthogonality. The H atom in the five-membered ring is disordered with equal occupancies at the two N atoms and the H atom of the methano­lic hy...

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Autores principales: Flores-Ramos, Miguel, Castillo, Rafael, Hernández-Campos, Alicia, Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914104/
https://www.ncbi.nlm.nih.gov/pubmed/24527009
http://dx.doi.org/10.1107/S1600536813033709
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author Flores-Ramos, Miguel
Castillo, Rafael
Hernández-Campos, Alicia
Flores-Alamo, Marcos
author_facet Flores-Ramos, Miguel
Castillo, Rafael
Hernández-Campos, Alicia
Flores-Alamo, Marcos
author_sort Flores-Ramos, Miguel
collection PubMed
description In the title compound, C(18)H(13)ClN(2)OS·CH(3)OH, the dihedral angle between the benzimidazole group and the naphth­yloxy moiety [82.89 (5)°] very near to orthogonality. The H atom in the five-membered ring is disordered with equal occupancies at the two N atoms and the H atom of the methano­lic hy­droxy group is disordered with equal occupancies over two sites at the O atom. The methanol mol­ecule acts as a hydrogen-bond acceptor for the amino H atom and donates a hydrogen bond to the nonprotonated ring N atom. As a result, chains are formed running along the a axis.
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spelling pubmed-39141042014-02-13 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate Flores-Ramos, Miguel Castillo, Rafael Hernández-Campos, Alicia Flores-Alamo, Marcos Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(13)ClN(2)OS·CH(3)OH, the dihedral angle between the benzimidazole group and the naphth­yloxy moiety [82.89 (5)°] very near to orthogonality. The H atom in the five-membered ring is disordered with equal occupancies at the two N atoms and the H atom of the methano­lic hy­droxy group is disordered with equal occupancies over two sites at the O atom. The methanol mol­ecule acts as a hydrogen-bond acceptor for the amino H atom and donates a hydrogen bond to the nonprotonated ring N atom. As a result, chains are formed running along the a axis. International Union of Crystallography 2013-12-21 /pmc/articles/PMC3914104/ /pubmed/24527009 http://dx.doi.org/10.1107/S1600536813033709 Text en © Flores-Ramos et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Flores-Ramos, Miguel
Castillo, Rafael
Hernández-Campos, Alicia
Flores-Alamo, Marcos
5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title_full 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title_fullStr 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title_full_unstemmed 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title_short 5-Chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1H-benzimidazole methanol monosolvate
title_sort 5-chloro-2-methyl­sulfanyl-6-(naphtha­len-1-yl­oxy)-1h-benzimidazole methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914104/
https://www.ncbi.nlm.nih.gov/pubmed/24527009
http://dx.doi.org/10.1107/S1600536813033709
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