(1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one

The absolute configuration of the title compound, C(16)H(24)O, has been deduced from the chemical pathway. The six-membered ring has a roughly half-chair conformation with the quaternary C atom as the flap. The seven-membered ring displays a chair conformation. In the crystal, there is a weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Bimoussa, Abdoullah, Auhmani, Aziz, Ait Itto, My Youssef, Daran, Jean-Claude, Abdelwahed, Auhmani
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914107/
https://www.ncbi.nlm.nih.gov/pubmed/24527013
http://dx.doi.org/10.1107/S1600536813034041
Descripción
Sumario:The absolute configuration of the title compound, C(16)H(24)O, has been deduced from the chemical pathway. The six-membered ring has a roughly half-chair conformation with the quaternary C atom as the flap. The seven-membered ring displays a chair conformation. In the crystal, there is a weak C—H⋯O hydrogen bond between the methyl­ene group of the cyclo­propane ring and the carbonyl group of a screw-axis-related mol­ecule, which builds up a zigzag-like chain along the b-axis direction.

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