(1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one

The absolute configuration of the title compound, C(16)H(24)O, has been deduced from the chemical pathway. The six-membered ring has a roughly half-chair conformation with the quaternary C atom as the flap. The seven-membered ring displays a chair conformation. In the crystal, there is a weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Bimoussa, Abdoullah, Auhmani, Aziz, Ait Itto, My Youssef, Daran, Jean-Claude, Abdelwahed, Auhmani
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914107/
https://www.ncbi.nlm.nih.gov/pubmed/24527013
http://dx.doi.org/10.1107/S1600536813034041
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author Bimoussa, Abdoullah
Auhmani, Aziz
Ait Itto, My Youssef
Daran, Jean-Claude
Abdelwahed, Auhmani
author_facet Bimoussa, Abdoullah
Auhmani, Aziz
Ait Itto, My Youssef
Daran, Jean-Claude
Abdelwahed, Auhmani
author_sort Bimoussa, Abdoullah
collection PubMed
description The absolute configuration of the title compound, C(16)H(24)O, has been deduced from the chemical pathway. The six-membered ring has a roughly half-chair conformation with the quaternary C atom as the flap. The seven-membered ring displays a chair conformation. In the crystal, there is a weak C—H⋯O hydrogen bond between the methyl­ene group of the cyclo­propane ring and the carbonyl group of a screw-axis-related mol­ecule, which builds up a zigzag-like chain along the b-axis direction.
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spelling pubmed-39141072014-02-13 (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one Bimoussa, Abdoullah Auhmani, Aziz Ait Itto, My Youssef Daran, Jean-Claude Abdelwahed, Auhmani Acta Crystallogr Sect E Struct Rep Online Organic Papers The absolute configuration of the title compound, C(16)H(24)O, has been deduced from the chemical pathway. The six-membered ring has a roughly half-chair conformation with the quaternary C atom as the flap. The seven-membered ring displays a chair conformation. In the crystal, there is a weak C—H⋯O hydrogen bond between the methyl­ene group of the cyclo­propane ring and the carbonyl group of a screw-axis-related mol­ecule, which builds up a zigzag-like chain along the b-axis direction. International Union of Crystallography 2013-12-21 /pmc/articles/PMC3914107/ /pubmed/24527013 http://dx.doi.org/10.1107/S1600536813034041 Text en © Bimoussa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bimoussa, Abdoullah
Auhmani, Aziz
Ait Itto, My Youssef
Daran, Jean-Claude
Abdelwahed, Auhmani
(1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title_full (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title_fullStr (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title_full_unstemmed (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title_short (1R,3S,8R)-3,7,7,10-Tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
title_sort (1r,3s,8r)-3,7,7,10-tetra­methyl­tri­cyclo­[6.4.0.0(1,3)]dodec-9-en-11-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914107/
https://www.ncbi.nlm.nih.gov/pubmed/24527013
http://dx.doi.org/10.1107/S1600536813034041
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