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1-(2,3-Di­hydroxy­prop­yl)-4-{2-[4-(di­methyl­amino)­phen­yl]vin­yl}pyridinium chloride

The title compound, C(18)H(23)N(2)O(2) (+)·Cl(−), crystallizes with two independent cations and anions per cell. Each cation has twofold rotational disorder about the linking vinyl groups but with unequal occupancies [0.963 (5):0.037 (5) and 0.860 (8):0.140 (8)]. The two independent cations are clos...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Bhuiyan, M. Delower H., Kay, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914108/
https://www.ncbi.nlm.nih.gov/pubmed/24527014
http://dx.doi.org/10.1107/S1600536813033254
Descripción
Sumario:The title compound, C(18)H(23)N(2)O(2) (+)·Cl(−), crystallizes with two independent cations and anions per cell. Each cation has twofold rotational disorder about the linking vinyl groups but with unequal occupancies [0.963 (5):0.037 (5) and 0.860 (8):0.140 (8)]. The two independent cations are close to being related by an inversion centre but the data does not support the expected centrosymmetric space-group assignment. The conclusion is that the differing rotational disorder has lead to an overall non-centrosymmetric lattice. In the crystal, the mol­ecules pack in layers parallel to (133) and (-13-3), chain-linked with motif C (1) (2)(7) by the di­hydroxy­propyl O–H⋯Cl⋯H–O hydrogen bonds. Other lattice binding is provided by O—H⋯Cl, C—H⋯Cl and C—H⋯N inter­actions.