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4-Nitrobenzoic acid–sulfathiazole (1/1)
In the crystal structure of the title compound, C(7)H(5)NO(4)·C(9)H(9)N(3)O(2)S(2), the sulfathiazole and 4-nitrobenzoic acid molecules are held together by short π–π contacts between the thiazole and nitrobenzene rings, with a centroid–centroid distance of 3.8226 (7) Å. The sulfathiazole mo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914109/ https://www.ncbi.nlm.nih.gov/pubmed/24527015 http://dx.doi.org/10.1107/S1600536813034004 |
Sumario: | In the crystal structure of the title compound, C(7)H(5)NO(4)·C(9)H(9)N(3)O(2)S(2), the sulfathiazole and 4-nitrobenzoic acid molecules are held together by short π–π contacts between the thiazole and nitrobenzene rings, with a centroid–centroid distance of 3.8226 (7) Å. The sulfathiazole molecules form dimers via N—H⋯N hydrogen bonds involving the thiazole and sulfonamide moieties, owing to the fact that sulfathizole exhibits amide–imide tautomerism. The N—H (amine) groups of two sulfathiazole molecules are linked to the two S=O groups of a sulfathiazole via N—H⋯O hydrogen bonds. Two molecules of coformer are held together by O—H⋯O hydrogen bonds. These units self-assemble, forming a three-dimensional network stabilized by (acid)C—H⋯π(sulfathiazole benzene ring) interactions. |
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