(E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine

The mol­ecule of the title hydrazine derivative, C(15)H(14)N(4)O(6), is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)°. The eth­oxy and hy­droxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) Å for the ten non-H a...

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Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Ruanwas, Pumsak, Kobkeatthawin, Thawanrat, Chidan Kumar, C. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914112/
https://www.ncbi.nlm.nih.gov/pubmed/24527018
http://dx.doi.org/10.1107/S1600536813033989
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chidan Kumar, C. S.
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chidan Kumar, C. S.
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title hydrazine derivative, C(15)H(14)N(4)O(6), is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)°. The eth­oxy and hy­droxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) Å for the ten non-H atoms]. Intra­molecular N—H⋯O and O—H⋯O(eth­oxy) hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked by O—H⋯O(nitro) hydrogen bonds into chains propagating in [010]. Weak aromatic π–π inter­actions, with centroid–centroid distances of 3.8192 (19) and 4.0491 (19) Å, are also observed.
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spelling pubmed-39141122014-02-13 (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine Fun, Hoong-Kun Chantrapromma, Suchada Ruanwas, Pumsak Kobkeatthawin, Thawanrat Chidan Kumar, C. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title hydrazine derivative, C(15)H(14)N(4)O(6), is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)°. The eth­oxy and hy­droxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation = 0.0153 (2) Å for the ten non-H atoms]. Intra­molecular N—H⋯O and O—H⋯O(eth­oxy) hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked by O—H⋯O(nitro) hydrogen bonds into chains propagating in [010]. Weak aromatic π–π inter­actions, with centroid–centroid distances of 3.8192 (19) and 4.0491 (19) Å, are also observed. International Union of Crystallography 2013-12-24 /pmc/articles/PMC3914112/ /pubmed/24527018 http://dx.doi.org/10.1107/S1600536813033989 Text en © Fun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Ruanwas, Pumsak
Kobkeatthawin, Thawanrat
Chidan Kumar, C. S.
(E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title_full (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title_fullStr (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title_full_unstemmed (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title_short (E)-1-(2,4-Di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
title_sort (e)-1-(2,4-di­nitro­phen­yl)-2-(3-eth­oxy-4-hy­droxy­benzyl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914112/
https://www.ncbi.nlm.nih.gov/pubmed/24527018
http://dx.doi.org/10.1107/S1600536813033989
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