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(E)-N′-(2-Chlorobenzylidene)-1-methyl-4-nitro-1H-pyrrole-2-carbohydrazide
In the title compound, C(13)H(11)ClN(4)O(3), the phenyl and pyrrolyl ring are linked by an acyl–hydrazone (R (2)C=N—N—CO—R) group, forming a slightly bent molecule: the dihedral angle subtended by the the phenyl and pyrrolyl rings is 8.46 (12)°. In the crystal, the three-dimensional supramolecula...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914118/ https://www.ncbi.nlm.nih.gov/pubmed/24527025 http://dx.doi.org/10.1107/S1600536813034119 |
Sumario: | In the title compound, C(13)H(11)ClN(4)O(3), the phenyl and pyrrolyl ring are linked by an acyl–hydrazone (R (2)C=N—N—CO—R) group, forming a slightly bent molecule: the dihedral angle subtended by the the phenyl and pyrrolyl rings is 8.46 (12)°. In the crystal, the three-dimensional supramolecular structure is assembled by N—H⋯O hydrogen bonding. Molecular sheets are formed parallel to (101) in a herringbone arrangement by weak van der Waals interactions; weak π–π [centroid–centroid phenyl–phenyl and pyrrolyl–pyrrolyl distances of 3.7816 (3) and 3.8946 (2) Å, respectively] interactions occur between neighbouring sheets. |
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