Analysis of Equation of States for the Suitability at High Pressure: MgO as an Example

A simple theoretical model is developed to study the high pressure behavior of solids and is applied to evaluate the pressure for MgO in case of large compression along with Shanker, Tait, Vinet, and Birch-Murnaghan equation of states (EOSs). These EOSs are also tested for the basic requirements revealed from the fundamental thermodynamics for solids in the limit of extreme compressions, as given by Stacey. It is found that for the high pressure compression behavior of MgO the present model, Tait, Vinet, and Birch-Murnaghan EOSs give the results compatible with the experimental data. It has also been found that in the regime of ultrahigh pressure the present model and Birch-Murnaghan EOS satisfy the Stacey criterion.