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Poly[(μ(3)-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
In the title compound, [Co(C(12)H(12)O(4))(C(5)H(5)N)(2)](n), the Co(II) cation is coordinated by four O atoms from three 5-tert-butylbenzene-1,3-dicarboxylate anions and two N atoms from pyridine molecules in a distorted octahedral geometry. One carboxylate group of the anionic ligand chelate...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3919544/ https://www.ncbi.nlm.nih.gov/pubmed/24526931 http://dx.doi.org/10.1107/S1600536813026640 |
Sumario: | In the title compound, [Co(C(12)H(12)O(4))(C(5)H(5)N)(2)](n), the Co(II) cation is coordinated by four O atoms from three 5-tert-butylbenzene-1,3-dicarboxylate anions and two N atoms from pyridine molecules in a distorted octahedral geometry. One carboxylate group of the anionic ligand chelates a Co(II) cation while another carboxylate group bridges two Co(II) cations, resulting in a polymeric layer parallel to (101). Weak C—H⋯O hydrogen bonds occur between adjacent polymeric layers. In the crystal, one of pyridine molecules is equally disordered over two positions. |
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