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Poly[(μ(3)-5-tert-butyl­benzene-1,3-di­carboxyl­ato)di­pyridine­cobalt(II)]

In the title compound, [Co(C(12)H(12)O(4))(C(5)H(5)N)(2)](n), the Co(II) cation is coordinated by four O atoms from three 5-tert-butyl­benzene-1,3-di­carboxyl­ate anions and two N atoms from pyridine mol­ecules in a distorted octa­hedral geometry. One carboxyl­ate group of the anionic ligand chelate...

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Detalles Bibliográficos
Autores principales: Noh, Kyungkyou, Kim, Jaheon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3919544/
https://www.ncbi.nlm.nih.gov/pubmed/24526931
http://dx.doi.org/10.1107/S1600536813026640
Descripción
Sumario:In the title compound, [Co(C(12)H(12)O(4))(C(5)H(5)N)(2)](n), the Co(II) cation is coordinated by four O atoms from three 5-tert-butyl­benzene-1,3-di­carboxyl­ate anions and two N atoms from pyridine mol­ecules in a distorted octa­hedral geometry. One carboxyl­ate group of the anionic ligand chelates a Co(II) cation while another carboxyl­ate group bridges two Co(II) cations, resulting in a polymeric layer parallel to (101). Weak C—H⋯O hydrogen bonds occur between adjacent polymeric layers. In the crystal, one of pyridine mol­ecules is equally disordered over two positions.