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Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3) O:O:O′)trizinc(II)]
The asymmetric unit of the title compound, [Zn(3)(HCO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), contains one Zn ion, one formate ligand, one N,N-dimethylformamide (DMF) ligand and one-third of a benzene-1,3,5-tricarboxylate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is c...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3919546/ https://www.ncbi.nlm.nih.gov/pubmed/24526933 http://dx.doi.org/10.1107/S1600536813028687 |
Sumario: | The asymmetric unit of the title compound, [Zn(3)(HCO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), contains one Zn ion, one formate ligand, one N,N-dimethylformamide (DMF) ligand and one-third of a benzene-1,3,5-tricarboxylate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is coordinated by one O atom from a DMF ligand, two O atoms from two btc ligands and three O atoms from three formate ligands in a distorted octahedral geometry. The Zn(II) atoms are connected by the formate and btc ligands, forming hexanuclear cores, which are linked by btc ligands, constructing a two-dimensional layered network along the ab plane. |
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