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Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3) O:O:O′)trizinc(II)]
The asymmetric unit of the title compound, [Zn(3)(HCO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), contains one Zn ion, one formate ligand, one N,N-dimethylformamide (DMF) ligand and one-third of a benzene-1,3,5-tricarboxylate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3919546/ https://www.ncbi.nlm.nih.gov/pubmed/24526933 http://dx.doi.org/10.1107/S1600536813028687 |
| _version_ | 1782303044502814720 |
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| author | Sim, Jaeung Kim, Taemin Yang, Jin Kuk |
| author_facet | Sim, Jaeung Kim, Taemin Yang, Jin Kuk |
| author_sort | Sim, Jaeung |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Zn(3)(HCO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), contains one Zn ion, one formate ligand, one N,N-dimethylformamide (DMF) ligand and one-third of a benzene-1,3,5-tricarboxylate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is coordinated by one O atom from a DMF ligand, two O atoms from two btc ligands and three O atoms from three formate ligands in a distorted octahedral geometry. The Zn(II) atoms are connected by the formate and btc ligands, forming hexanuclear cores, which are linked by btc ligands, constructing a two-dimensional layered network along the ab plane. |
| format | Online Article Text |
| id | pubmed-3919546 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39195462014-02-13 Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3) O:O:O′)trizinc(II)] Sim, Jaeung Kim, Taemin Yang, Jin Kuk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(3)(HCO(2))(3)(C(9)H(3)O(6))(C(3)H(7)NO)(3)](n), contains one Zn ion, one formate ligand, one N,N-dimethylformamide (DMF) ligand and one-third of a benzene-1,3,5-tricarboxylate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is coordinated by one O atom from a DMF ligand, two O atoms from two btc ligands and three O atoms from three formate ligands in a distorted octahedral geometry. The Zn(II) atoms are connected by the formate and btc ligands, forming hexanuclear cores, which are linked by btc ligands, constructing a two-dimensional layered network along the ab plane. International Union of Crystallography 2013-10-26 /pmc/articles/PMC3919546/ /pubmed/24526933 http://dx.doi.org/10.1107/S1600536813028687 Text en © Sim et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sim, Jaeung Kim, Taemin Yang, Jin Kuk Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6) O (1):O (1′):O (3):O (3′):O (5):O (5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3) O:O:O′)trizinc(II)] |
| title | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3)
O:O:O′)trizinc(II)] |
| title_full | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3)
O:O:O′)trizinc(II)] |
| title_fullStr | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3)
O:O:O′)trizinc(II)] |
| title_full_unstemmed | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3)
O:O:O′)trizinc(II)] |
| title_short | Poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
O
(1):O
(1′):O
(3):O
(3′):O
(5):O
(5′))tris(N,N-dimethylformamide-κO)tris(μ(3)-formato-κ(3)
O:O:O′)trizinc(II)] |
| title_sort | poly[(μ(6)-benzene-1,3,5-tricarboxylato-κ(6)
o
(1):o
(1′):o
(3):o
(3′):o
(5):o
(5′))tris(n,n-dimethylformamide-κo)tris(μ(3)-formato-κ(3)
o:o:o′)trizinc(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3919546/ https://www.ncbi.nlm.nih.gov/pubmed/24526933 http://dx.doi.org/10.1107/S1600536813028687 |
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