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Probing substrate influence on graphene by analyzing Raman lineshapes
We provide a new approach to identify the substrate influence on graphene surface. Distinguishing the substrate influences or the doping effects of charged impurities on graphene can be realized by optically probing the graphene surfaces, included the suspended and supported graphene. In this work,...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3924919/ https://www.ncbi.nlm.nih.gov/pubmed/24506825 http://dx.doi.org/10.1186/1556-276X-9-64 |
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author | Huang, Chen-Han Lin, Hsing-Ying Huang, Cheng-Wen Liu, Yi-Min Shih, Fu-Yu Wang, Wei-Hua Chui, Hsiang-Chen |
author_facet | Huang, Chen-Han Lin, Hsing-Ying Huang, Cheng-Wen Liu, Yi-Min Shih, Fu-Yu Wang, Wei-Hua Chui, Hsiang-Chen |
author_sort | Huang, Chen-Han |
collection | PubMed |
description | We provide a new approach to identify the substrate influence on graphene surface. Distinguishing the substrate influences or the doping effects of charged impurities on graphene can be realized by optically probing the graphene surfaces, included the suspended and supported graphene. In this work, the line scan of Raman spectroscopy was performed across the graphene surface on the ordered square hole. Then, the bandwidths of G-band and 2D-band were fitted into the Voigt profile, a convolution of Gaussian and Lorentzian profiles. The bandwidths of Lorentzian parts were kept as constant whether it is the suspended and supported graphene. For the Gaussian part, the suspended graphene exhibits much greater Gaussian bandwidths than those of the supported graphene. It reveals that the doping effect on supported graphene is stronger than that of suspended graphene. Compared with the previous studies, we also used the peak positions of G bands, and I(2D)/I(G) ratios to confirm that our method really works. For the suspended graphene, the peak positions of G band are downshifted with respect to supported graphene, and the I(2D)/I(G) ratios of suspended graphene are larger than those of supported graphene. With data fitting into Voigt profile, one can find out the information behind the lineshapes. |
format | Online Article Text |
id | pubmed-3924919 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | Springer |
record_format | MEDLINE/PubMed |
spelling | pubmed-39249192014-02-20 Probing substrate influence on graphene by analyzing Raman lineshapes Huang, Chen-Han Lin, Hsing-Ying Huang, Cheng-Wen Liu, Yi-Min Shih, Fu-Yu Wang, Wei-Hua Chui, Hsiang-Chen Nanoscale Res Lett Nano Express We provide a new approach to identify the substrate influence on graphene surface. Distinguishing the substrate influences or the doping effects of charged impurities on graphene can be realized by optically probing the graphene surfaces, included the suspended and supported graphene. In this work, the line scan of Raman spectroscopy was performed across the graphene surface on the ordered square hole. Then, the bandwidths of G-band and 2D-band were fitted into the Voigt profile, a convolution of Gaussian and Lorentzian profiles. The bandwidths of Lorentzian parts were kept as constant whether it is the suspended and supported graphene. For the Gaussian part, the suspended graphene exhibits much greater Gaussian bandwidths than those of the supported graphene. It reveals that the doping effect on supported graphene is stronger than that of suspended graphene. Compared with the previous studies, we also used the peak positions of G bands, and I(2D)/I(G) ratios to confirm that our method really works. For the suspended graphene, the peak positions of G band are downshifted with respect to supported graphene, and the I(2D)/I(G) ratios of suspended graphene are larger than those of supported graphene. With data fitting into Voigt profile, one can find out the information behind the lineshapes. Springer 2014-02-07 /pmc/articles/PMC3924919/ /pubmed/24506825 http://dx.doi.org/10.1186/1556-276X-9-64 Text en Copyright © 2014 Huang et al.; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited. |
spellingShingle | Nano Express Huang, Chen-Han Lin, Hsing-Ying Huang, Cheng-Wen Liu, Yi-Min Shih, Fu-Yu Wang, Wei-Hua Chui, Hsiang-Chen Probing substrate influence on graphene by analyzing Raman lineshapes |
title | Probing substrate influence on graphene by analyzing Raman lineshapes |
title_full | Probing substrate influence on graphene by analyzing Raman lineshapes |
title_fullStr | Probing substrate influence on graphene by analyzing Raman lineshapes |
title_full_unstemmed | Probing substrate influence on graphene by analyzing Raman lineshapes |
title_short | Probing substrate influence on graphene by analyzing Raman lineshapes |
title_sort | probing substrate influence on graphene by analyzing raman lineshapes |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3924919/ https://www.ncbi.nlm.nih.gov/pubmed/24506825 http://dx.doi.org/10.1186/1556-276X-9-64 |
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