Metal Hydrides Form Halogen Bonds: Measurement of Energetics of Binding

[Image: see text] The formation of halogen bonds from iodopentafluorobenzene and 1-iodoperfluorohexane to a series of bis(η(5)-cyclopentadienyl)metal hydrides (Cp(2)TaH(3), 1; Cp(2)MH(2), M = Mo, 2, M = W, 3; Cp(2)ReH, 4; Cp(2)Ta(H)CO, 5; Cp = η(5)-cyclopentadienyl) is demonstrated by (1)H NMR spect...

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Detalles Bibliográficos
Autores principales: Smith, Dan A., Brammer, Lee, Hunter, Christopher A., Perutz, Robin N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3928989/
https://www.ncbi.nlm.nih.gov/pubmed/24380577
http://dx.doi.org/10.1021/ja4121499

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3928989/
https://www.ncbi.nlm.nih.gov/pubmed/24380577
http://dx.doi.org/10.1021/ja4121499

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